From Traditional to Novel Printed Electrochromic Devices: Material, Structure and Device

Abstract

Electrochromic materials have been considered as a new way to achieve energy savings in the building sector due to their potential applications in smart windows, cars, aircrafts, etc. However, the high cost of manufacturing ECDs using the conventional manufacturing methods has limited its commercialization. It is the advantages of low cost as well as resource saving, green environment protection, flexibility and large area production that make printing electronic technology fit for manufacturing electrochromic devices. This paper reviews the progress of research on printed electrochromic devices (ECDs), detailing the preparation of ECDs by screen printing, inkjet printing and 3D printing, using the scientific properties of discrete definition printing method. Up to now, screen printing holds the largest share in the electrochromic industry due to its low cost and large ink output nature, which makes it suitable especially for printing on large surfaces. Though inkjet printing has the advantages of high precision and the highest coloration efficiency (CE) can be up to 542 ± 10 cm2C–1, it has developed smoothly, and has not shown rigid needs. Inkjet printing is suitable for the personalized printing production of high precision and small batch electronic devices. Since 3D printing is a new manufacturing technology in the 21st century, with the characteristics of integrated molding and being highly controllable, which make it suitable for customized printing of complex devices, such as all kinds of sensors, it has gained increasing attention in the past decade. Finally, the possibility of combining screen printing with inkjet printing to produce high performance ECDs is discussed.

Toward Next‐Generation Smart Windows: An In‐depth Analysis of Dual‐Band Electrochromic Materials and Devices

“…[200] To enhance coating efficiency, slot-die coating and knife coating have become prevalent in industrial settings. [208][209][210][211] Both knife coating and slot-die coating ensure even distribution of ink across large, flat surfaces. But knife coating is only suitable for largescale processing without any patterns, while slot-die coating allows for variable-width strip coatings through installing a meniscus guide in the middle of the slot-die.…”

Inkjet printing for smart electrochromic devices

“…IJP technology can achieve precise control of the printed layer, but at the same time, it is also necessary to consider the impact of IJP on the performance of the electrolyte, to ensure the high transmittance and high ionic conductivity of printed electrolyte. 23 ECD requires the electrochromic layer and ion storage layer to be in close contact with electrolyte. Therefore, it is necessary to properly adjust IJP parameters to achieve uniform electrolyte deposition to ensure uniform thickness.…”

Effect of metal dopants on the electrochromic performance of hydrothermally-prepared tungsten oxide materials

“…4 Typically, EC devices are composed of multiple layers, including a working electrode layer, ion conductive layer, and ion storage layer. 5 The underlying process of EC is widely accepted to be a result of insertion/de-insertion of electrons and cations (e.g. Li + , Na + or H + ) in the oxide matrix.…”