Abstract:Abstract. Boreal headwaters are often lined by strips of highly organic soils, which are the last terrestrial environment to leave an imprint on discharging groundwater before it enters a stream. Because these riparian soils are so different from the Podzol soils that dominate much of the boreal landscape, they are known to have a major impact on the biogeochemistry of important elements such as C, N, P and Fe and the transfer of these elements from terrestrial to aquatic ecosystems. For most elements, however… Show more
“…10 One puzzle that still needs to be resolved is how organic rich riparian soils can remain such an important supplier for so many natural and anthropogenic metals and organic compounds, when concentrations of these solutes are often up to 100 times lower in the upland soils that often serve as the original source. 49,58 We do know that, at the present rate of DOC export, the riparian organic carbon pool can continue to sustain several hundred years of losses without any new organic carbon production. 59 However, we do not currently understand how climate change and other environmental stressors may affect this pool in the future.…”
Catchment science plays a critical role in the protection of water resources in the face of ongoing changes in climate, long‐range transport of air pollutants, and land use. Addressing these challenges, however, requires improved understanding of how, when, and where changes in water quantity and quality occur within river networks. To reach these goals, we must recognize how different catchment features are organized to regulate surface chemistry at multiple scales, from processes controlling headwaters, to the downstream mixing of water from multiple landscape sources and deep aquifers. Here we synthesize 30‐years of hydrological and biogeochemical research from the Krycklan catchment study (KCS) in northern Sweden to demonstrate the benefits of coupling long‐term monitoring with multi‐scale research to advance our understanding of catchment functioning across space and time. We show that the regulation of hydrological and biogeochemical patterns in the KCS can be decomposed into four, hierarchically structured landscape features that include: (1) transmissivity and reactivity of dominant source layers within riparian soils, (2) spatial arrangement of groundwater input zones that govern water and solute fluxes at reach‐ to segment‐scales, (3) landscape scale heterogeneity (forests, mires, and lakes) that generates unique biogeochemical signals downstream, and (4) broad‐scale mixing of surface streams with deep groundwater contributions. While this set of features are perhaps specific to the study region, analogous hierarchical controls are likely to be widespread. Resolving these scale dependent processes is important for predicting how, when, and where different environmental changes may influence patterns of surface water chemistry within river networks. WIREs Water 2018, 5:e1265. doi: 10.1002/wat2.1265
This article is categorized under:
Science of Water > Hydrological Processes
Science of Water > Water and Environmental Change
Science of Water > Methods
“…10 One puzzle that still needs to be resolved is how organic rich riparian soils can remain such an important supplier for so many natural and anthropogenic metals and organic compounds, when concentrations of these solutes are often up to 100 times lower in the upland soils that often serve as the original source. 49,58 We do know that, at the present rate of DOC export, the riparian organic carbon pool can continue to sustain several hundred years of losses without any new organic carbon production. 59 However, we do not currently understand how climate change and other environmental stressors may affect this pool in the future.…”
Catchment science plays a critical role in the protection of water resources in the face of ongoing changes in climate, long‐range transport of air pollutants, and land use. Addressing these challenges, however, requires improved understanding of how, when, and where changes in water quantity and quality occur within river networks. To reach these goals, we must recognize how different catchment features are organized to regulate surface chemistry at multiple scales, from processes controlling headwaters, to the downstream mixing of water from multiple landscape sources and deep aquifers. Here we synthesize 30‐years of hydrological and biogeochemical research from the Krycklan catchment study (KCS) in northern Sweden to demonstrate the benefits of coupling long‐term monitoring with multi‐scale research to advance our understanding of catchment functioning across space and time. We show that the regulation of hydrological and biogeochemical patterns in the KCS can be decomposed into four, hierarchically structured landscape features that include: (1) transmissivity and reactivity of dominant source layers within riparian soils, (2) spatial arrangement of groundwater input zones that govern water and solute fluxes at reach‐ to segment‐scales, (3) landscape scale heterogeneity (forests, mires, and lakes) that generates unique biogeochemical signals downstream, and (4) broad‐scale mixing of surface streams with deep groundwater contributions. While this set of features are perhaps specific to the study region, analogous hierarchical controls are likely to be widespread. Resolving these scale dependent processes is important for predicting how, when, and where different environmental changes may influence patterns of surface water chemistry within river networks. WIREs Water 2018, 5:e1265. doi: 10.1002/wat2.1265
This article is categorized under:
Science of Water > Hydrological Processes
Science of Water > Water and Environmental Change
Science of Water > Methods
“…Consequently, groundwater chemistry is expected to vary throughout the catchment. Hillslope and riparian groundwater chemistry tend to differ due to differences in biogeochemical processes (e.g., Cirmo & McDonnell, ) and the accumulation of organic material in the riparian zone (Lidman, Boily, Laudon, & Köhler, ; McGlynn, McDonnell, Stewart, & Seibert, ). However, even riparian zone groundwater chemistry can vary significantly over very short distances.…”
Topography and landscape characteristics affect the storage and release of water and, thus, groundwater dynamics and chemistry. Quantification of catchment scale variability in groundwater chemistry and groundwater dynamics may therefore help to delineate different groundwater types and improve our understanding of which parts of the catchment contribute to streamflow. We sampled shallow groundwater from 34 to 47 wells and streamflow at seven locations in a 20‐ha steep mountainous catchment in the Swiss pre‐Alps, during nine baseflow snapshot campaigns. The spatial variability in electrical conductivity, stable water isotopic composition, and major and trace ion concentrations was large and for almost all parameters larger than the temporal variability. Concentrations of copper, zinc, and lead were highest at sites that were relatively dry, whereas concentrations of manganese and iron were highest at sites that had persistent shallow groundwater levels. The major cation and anion concentrations were only weakly correlated to individual topographic or hydrodynamic characteristics. However, we could distinguish four shallow groundwater types based on differences from the catchment average concentrations: riparian zone‐like groundwater, hillslopes and areas with small upslope contributing areas, deeper groundwater, and sites characterized by high magnesium and sulfate concentrations that likely reflect different bedrock material. Baseflow was not an equal mixture of the different groundwater types. For the majority of the campaigns, baseflow chemistry most strongly resembled riparian‐like groundwater for all but one subcatchment. However, the similarity to the hillslope‐type groundwater was larger shortly after snowmelt, reflecting differences in hydrologic connectivity. We expect that similar groundwater types can be found in other catchments with steep hillslopes and wet areas with shallow groundwater levels and recommend sampling of groundwater from all landscape elements to understand groundwater chemistry and groundwater contributions to streamflow.
“…Hillslope water is routed through preferential locations in the riparian zone, where its chemical composition can be altered before entering a stream (Ledesma et al, 2018;Lidman, Boily, Laudon, & Köhler, 2017).…”
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