“…Each feature, including the ground‐state bleaching and recovery, and the phosphorescence, exhibit similar TA lifetimes (Figure , right), which suggests that each peak relates to the same photoexcitation, ISC process and deactivation. This is attributed to the formation of the lowest triplet state, through prompt S 1 /T 1 ISC, and compares relatively well with the observed lifetime from time‐resolved emission measurements . Figure displays a comparison of TA spectra for the complexes [Ir(L1) 2 (bpy)]PF 6 , [Ir(L5) 2 (bpy)]PF 6 and [Ir(L6) 2 (bpy)]PF 6 .…”