From Alkenes to Cyclic Carbonates with a Stable Iron‐Cross‐Bridged Cyclam Catalyst

Yeamin, Md Bin; Annunziata, Alfonso; Ruffo, Francesco; Masdeu‐Bultó, Anna M.

doi:10.1002/slct.202400426

ChemistrySelect

2024

DOI: 10.1002/slct.202400426

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From Alkenes to Cyclic Carbonates with a Stable Iron‐Cross‐Bridged Cyclam Catalyst

Md Bin Yeamin,

Alfonso Annunziata,

Francesco Ruffo

et al.

Abstract: A stable iron(III) complex with the cross‐bridged cyclam 4,11‐dimethyl‐1,4,8,11‐tetraazabicyclo[6.6.2]hexadecane catalyzes the epoxidation of aromatic alkenes and the fixation of CO2 into cyclic carbonates. Best results were obtained for styrene conversion to styrene carbonate.

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From Alkenes to Cyclic Carbonates with a Stable Iron‐Cross‐Bridged Cyclam Catalyst

Abstract: A stable iron(III) complex with the cross‐bridged cyclam 4,11‐dimethyl‐1,4,8,11‐tetraazabicyclo[6.6.2]hexadecane catalyzes the epoxidation of aromatic alkenes and the fixation of CO2 into cyclic carbonates. Best results were obtained for styrene conversion to styrene carbonate.

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References 49 publications

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