2021
DOI: 10.1039/d1nr03136h
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Frequency stable dielectric constant with reduced dielectric loss of one-dimensional ZnO–ZnS heterostructures

Abstract: ZnO–ZnS heterostructure is developed which shows frequency stable dielectric response at ≥103 Hz due to coupling of the bare charges in the form of overlapping large polaron and Zn2+–VO dipoles present at ZnO–ZnS heterostructure interface.

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Cited by 7 publications
(2 citation statements)
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“…The third binding energy peak at 533.6 eV is characteristic of oxygen vacancies in ZnO. 60 UV-vis diffuse reflectance spectroscopy (DRS) was used to investigate the photoabsorption tendency of synthesized pristine MoS 2 , ZnO and the MoS 2 -ZnO heterostructure (Fig. S3a-c, ESI †).…”
Section: Resultsmentioning
confidence: 99%
“…The third binding energy peak at 533.6 eV is characteristic of oxygen vacancies in ZnO. 60 UV-vis diffuse reflectance spectroscopy (DRS) was used to investigate the photoabsorption tendency of synthesized pristine MoS 2 , ZnO and the MoS 2 -ZnO heterostructure (Fig. S3a-c, ESI †).…”
Section: Resultsmentioning
confidence: 99%
“…Since the chemical shifts between Zn 2p spectra associated with different Zn electronic environments are characteristically on the order of 100 meV, even when considering disparate oxidation states of Zn ( Biesinger et al, 2010 ), the comparatively large separation of the Zn 2p doublets suggests that differential charging occurred within the NaBH 4 -synthesized samples, in turn indicating that they contained a mixture of materials with differing electrical conductivities. It is possible, for instance, that the inclusion of NaBH 4 during ZnS synthesis yielded discrete particles of ZnO, which is considerably more conductive than ZnS ( Zafar et al, 2021 ). One should note that as a highly surface-sensitive technique, XPS cannot detect species at a distance greater than 10 nm from the sample surface, in contrast to bulk characterisation procedures such as XRD.…”
Section: Resultsmentioning
confidence: 99%