2001
DOI: 10.1002/polb.1168
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Frequency‐dependent conductivity of interpenetrating polymer network composites of polypyrrole–poly(vinyl acetate)

Abstract: The frequency‐dependent conductivity of interpenetrating polymer network composites of polypyrrole (PPy) and poly(vinyl acetate) (PVAc) synthesized by FeCl3‐impregnated PVAc films being dipped into solutions of pyrrole in water was investigated over a frequency range of 100 Hz to 2 MHz and a temperature range of 110–300 K. For specimens with a PPy content less than the percolation threshold, the quantum mechanical tunneling of electrons was the conduction mechanism. For specimens with a higher PPy content, cor… Show more

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Cited by 31 publications
(8 citation statements)
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“…Following the procedure described by Bhattacharya et al,57 the s values as a function of frequency for each measured temperature were obtained. It is noted that to evaluate the exponent s , only frequencies above the region where the earlier discussed relaxation process appears, were considered.…”
Section: Resultsmentioning
confidence: 99%
“…Following the procedure described by Bhattacharya et al,57 the s values as a function of frequency for each measured temperature were obtained. It is noted that to evaluate the exponent s , only frequencies above the region where the earlier discussed relaxation process appears, were considered.…”
Section: Resultsmentioning
confidence: 99%
“…The following formulae were used to determine the AC conductivity as follows: [ 40 , 41 , 42 , 43 ]: …”
Section: Resultsmentioning
confidence: 99%
“…It is significant to investigate the frequency influences on the AC electrical conductivity to describe the Er2O3-ZnO nanocomposite materials' conduction mechanism at different Erbium doping ratios. To compute the AC conductivity of the material under process, the next equations were applied (Murowski and Barczynski 1995;Bhattacharyya et al 2001;Jali et al 2007;Bobnar et al 2004):…”
Section: Optical Diffused Reflectance (Odr)mentioning
confidence: 99%