A molecular beam spectrometer capable of achieving sub-Doppler resolution at 2 eV ͑ϳ18 000 cm Ϫ1 ) of vibrational excitation is described and its performance demonstrated using the CH stretch chromophore of HCN. Two high finesse resonant power-buildup cavities are used to excite the molecules using a sequential double resonance technique. A vϭ0→2 transition is first saturated using a 1.5 m color center laser, whereupon a fraction of the molecules is further excited to the vϭ6 level using an amplitude modulated Ti:Al 2 O 3 laser. The energy absorbed by the molecules is detected downstream of both excitation points by a cryogenically cooled bolometer using phase sensitive detection. A resolution of approximately 15 MHz ͑i.e., three parts in 10 8 ) is demonstrated by recording a rotational line in the vϭ6 manifold of HCN. Scan speeds of up to several cm Ϫ1 /h were obtained, with signal-to-noise ratios in excess of 100. The high signal-to-noise ratio and a dynamic range of 6ϫ10 4 means that future experiments to study statistical intramolecular vibrational energy redistribution in small molecules and unimolecular isomerizations can be attempted. We would also like to point out that, with improved metrology in laser wavelengths, this instrument can also be used to provide improved secondary frequency standards based upon the rovibrational spectra of molecules.