Frequency and composition dependency of optical and dielectric properties of PMMA/boehmite nano-hybrid prepared via facile aqueous one-pot process

Abstract

Optical properties of PMMA/boehmite nano-hybrid synthesized directly from their relevant precursors via facile aqueous one-pot process is studied. Silane coupling agent was applied to make compatible chemically the organic–inorganic counterparts. The chemical bond of SiOAl as the main link between organic and inorganic moieties was confirmed by Fourier transforms infrared (FTIR) spectra. The chemical bond of Si–O–Al as the main link between organic and inorganic moieties. Determining the refractive and absorption index, real and imaginary parts of dielectric constant, energy loss function, and their distribution for PMMA/boehmite nano-hybrid as a function of boehmite loading was assessed in the range of 12–120 THz using FTIR data and Kramers–Kronig relations. The inorganic/organic weight ratio varied from 0.7% to 5% and its impact on optical features was evaluated. It was demonstrated that the optical features of hybrids are frequency-dependent and less affected from boehmite incorporation.

Aluminum oxyhydroxide-doped PMMA hybrids powder prepared via facile one-pot method towards copper ion removal from aqueous solution

“…Since the adsorption peak at 1636 cm −1 cannot be seen, the C=C double bond has been changed to the single bond in both monomer and silane. The asymmetric and symmetric stretching vibrations of the methylene and methyl species in 2850-3050 cm −1 are identified [21] and show intensities growing with samples containing more silane (more BO). On the other hand, the increasing trend in adsorption at 2958 cm −1 [22] can be clarified with more involvement of silane coupling agents with raising the BO content.…”