It is highly desirable to apply magnesium-based alloys, which are the lightest structural metallic materials, in structural parts because of their high strength-to-density ratio, high energy absorption, and good castability. AM-series magnesium alloys, which belong to the MgÀAl system, are the most widely used commercial magnesium alloys, but they have poor thermal stability of the Mg 17 Al 12 phase (with a eutectic temperature of 437°C), and their discontinuous precipitation can result in substantial grain boundary sliding at elevated temperatures. These properties make AM-series alloys generally unsuitable for use above 150°C, and even at this temperature, considerable losses in strength are evident, rendering them inadequate for major power train applications. [1][2][3][4][5][6][7] One possible approach to improving the thermal stability and creep resistance of these kinds of alloys involves introducing alloying elements with higher affinities to aluminum to suppress the formation of the Mg 17 Al 12 phase. Introducing secondary phase particles to pin the grain boundaries and prevent sliding phenomenon is another such approach. One significant discovery that has emerged from the considerable efforts expended more than 10 years is the beneficial effect of rare-earth elements (REs) or yttrium on the mechanical properties of magnesium alloys, including their strength and creep resistance of magnesium alloys. [8][9][10][11] For this reason, magnesium alloys with RE and with Y þ RE (WE) are widely used in several technological applications. However, RE and Y are usually considered to be too high priced.The addition of low-cost calcium, which provides a finer solidified microstructure in the Mg alloy, [12][13][14][15][16] is also an effective way to improve the mechanical properties of magnesium alloys at elevated temperatures. The addition of other inexpensive elements such as bismuth could significantly increase the tensile strength and creep resistance, as reported by Yuan et al. [17,18] However, very few current reports have addressed to the effects of the addition of calcium and bismuth to AM50 magnesium alloys on their microstructures and mechanical properties. Hence, to understand the function of new secondary phases in the microstructures on its properties of magnesium alloys, the present work attempts to analyze the relationship between the microstructure and the properties when both calcium and bismuth are added into an AM50 alloy, to obtain the optimal addition of calcium plus bismuth for AM50 alloy. This can provide the basis for further applications of high-temperature magnesium alloys.
ExperimentalCommercial as-cast AM50 magnesium alloy ingot, highpurity (99.5%) calcium granules (99.5%), and bismuth granules (99.0%) were used to prepare the AM50-xBi-yCa alloy using a resistance crucible furnace melting under the protection of a mixed gas atmosphere of 99.5% CO 2 and 0.5% SF 6 (vol%). The chemical compositions of the experimental alloys with varying concentrations of calcium (0, 1, 2, and 3 wt %) and bis...