2021
DOI: 10.1111/jace.17871
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Freeze‐cast honeycomb structures via gravity‐enhanced convection

Abstract: The effect of gravity on directional solidification was investigated in solution-based freeze casting. A preceramic siloxane-based polymer was freeze-cast with a cyclohexene solvent from two different directions: that against the direction of the gravitational force and that in concert with gravitational force. Since the density of preceramic polymer is higher than the solvent, the segregated polymer creates a denser solution ahead of the freezing front than the underlying solution when the freezing direction … Show more

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Cited by 2 publications
(1 citation statement)
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“…However, these conventional processing techniques offer a limited range of achievable pore morphologies, pore directionality, and pore window size distribution. Solution-based freeze-casting arises as a flexible sacrificial templating method that allows the creation of a wider range of pore structures [ 15 , 31 ]. This process starts with dissolving a preceramic polymer in an organic solvent followed by freezing this polymer solution.…”
Section: Introductionmentioning
confidence: 99%
“…However, these conventional processing techniques offer a limited range of achievable pore morphologies, pore directionality, and pore window size distribution. Solution-based freeze-casting arises as a flexible sacrificial templating method that allows the creation of a wider range of pore structures [ 15 , 31 ]. This process starts with dissolving a preceramic polymer in an organic solvent followed by freezing this polymer solution.…”
Section: Introductionmentioning
confidence: 99%