2021
DOI: 10.1002/macp.202100087
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Free Volumes and Grüneisen Parameters in Mixed‐Tacticity Polyhydroxybutyrates

Abstract: Recently, nonlinear progressions of mechanical and thermal properties of mixed‐tacticity polyhydroxybutyrates have been discovered with their fraction of meso diads fmeso. Characteristic fmeso is traced by a measure trueλ̂ of polymer chain segment length disturbance, due to the inclusion of S enantiomers in chains consisting otherwise of R monomers. In this article, the material compositions' thermal expansion coefficients are reported on as determined by X‐ray diffraction and connect the qualitative trueλ̂ to… Show more

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