A promising electrochemical nitrite sensor was fabricated by immobilizing Au@Fe 3 O 4 nanoparticles on the surface of l-cysteine modified glassy carbon electrode, which was characterized by scanning electron microscopy, X-ray photoelectron spectroscopy, electrochemical impedance spectroscopy and cyclic voltammetry. The proposed sensor exhibited excellent electrocatalytic activity toward nitrite oxidation. The kinetic parameters of the electrode reaction process were calculated, (1 -a)n a was 0.38 and the heterogeneous electron transfer coefficient (k) was 0.13 cm s
À1. The detection conditions such as supporting electrolyte and pH value were optimized. Under the optimized conditions, the linear range for the determination of nitrite was 3.6 Â 10 À6 to 1.0 Â 10 À2 M with a detection limit of 8.2 Â 10 À7 M (S/ N ¼ 3). Moreover, the as-prepared electrode displayed good stability, repeatability and selectivity for promising practical applications.