1966
DOI: 10.1103/physrev.144.734
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Free-Carrier Absorption in Reduced SrTiO3

Abstract: Optical absorption in stoichiometric and reduced, semiconducting single crystals of SrTi0 3 has been measured in the region 0.4-5 ju at room temperature and 77°K. Reduced crystals show a rapid increase of absorption with increasing wavelength beyond 0.6 fx, characteristic of free-carrier absorption. The absorption is proportional to electron concentration and nearly independent of temperature. For wavelengths between 0.7 and 2.5 fx the absorption varies as X 2 -5 , suggesting that longitudinal-optical-mode sca… Show more

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Cited by 119 publications
(39 citation statements)
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“…at 2 K, decreases with temperature rapidly and varies in accordance with certain power laws above 30 K, where the scattering of electrons by polar optical phonons dominates and results in µ ∝ T −β [19]. The effect of the structural phase transition in STO at ∼105 K on the mobility can be apparently seen from the linear fittings owing to the variation in the activation of phonon modes.…”
Section: Electrical Propertiesmentioning
confidence: 70%
“…at 2 K, decreases with temperature rapidly and varies in accordance with certain power laws above 30 K, where the scattering of electrons by polar optical phonons dominates and results in µ ∝ T −β [19]. The effect of the structural phase transition in STO at ∼105 K on the mobility can be apparently seen from the linear fittings owing to the variation in the activation of phonon modes.…”
Section: Electrical Propertiesmentioning
confidence: 70%
“…2͑c͒ and 3͑b͔͒. The strength of this absorption is known to scale with the charge carrier concentration [14][15][16] and was thus consistent with the electrical conductivity of the crystals. In addition, an absorption peak at 2.92 eV ͑424 nm͒ was observed ͓see Fig.…”
Section: -13mentioning
confidence: 85%
“…8, the absorption spectra of the (film+substrate) structure shows a broad peak centered around 2.4 eV, and a smaller one around 1.7 eV, whereas both peaks are absent in the virgin substrate. These peaks lying below the 3.2 eV band-gap are characteristic of reduced STO bulk crystals, and are systematically attributed to the presence of F centers caused by oxygen vacancies 49 . Based on the experimental data that evidence the presence of oxygen vacancies in STO, we propose a simple model to quantify this effect and to explain the macroscopic transport properties including the apparent metalto-semiconducting transition.…”
mentioning
confidence: 96%
“…Since the measure of optical properties can reveal the presence of oxygen vacancies in STO 49 , we have measured the optical absorption of the sample grown at 700…”
mentioning
confidence: 99%