Fracture Process of In-situ Polymerization Modified Cementitious Materials

Abstract

By regulating cement hydration reaction and organic monomer polymerization, the strength and deformability of in-situ polymerization modified cement-based materials are greatly improved. However, the fracture processes of this type of organic-inorganic composites have not been systematically investigated. In this work, sodium acrylate (SA) monomer in-situ polymerization modified cementitious composites (iPSA) were fabricated. Three-point bending (TPB) test was conducted with digital image correlation (DIC) technique for characterizing the fracture process zone (FPZ). Microscopic test was conducted to unravel the crosslinked organic-inorganic composite structures in the iPSA matrix. Results showed that an obvious strain concentration region occurred and grew at the notch tip of the iPSA beams with load. The gradually expanding width of FPZ was normally distributed. Microscopic test suggested that the physical interlinks between the cement hydrates and sodium polyacrylate may resist again the FPZ development of iPSA. The findings of this work would deepen the understandings of fracture process of polymer modified cementitious composites with broad engineering applications.