Degenerate conduction-band minima, or 'valleys', in materials such as Si, AlAs, graphene, and MoS2 allow them to host two-dimensional electron systems (2DESs) that can access a valley degree of freedom. These multivalley 2DESs present exciting opportunities for both pragmatic and fundamental research alike because not only are they a platform for valleytronic devices, but they also provide a tool to tune and investigate the properties of complex many-body ground states. Here, we report ultra-high quality, modulation doped AlAs quantum wells containing 2DESs that occupy two anisotropic valleys and have electron mobilities peaking at 2.4 × 10 6 cm 2 V −1 s −1 at a density of 2.2 × 10 11 cm −2 . This is more than an order of magnitude improvement in mobility over previous results. The unprecedented quality of our samples is demonstrated by magneto-transport data that show high-order fractional quantum Hall minima up to the Landau level filling ν = 8/17, and even the elusive ν = 1/5 quantum Hall state.