Abstract:ABSTRACT:The correctness of the molecular weight distribution (MWD) of a poly(dimethyl diallyl ammonium chloride) type was shown in the frame-work of the dynamic distribution function of the irreversible aggregation clustercluster model. The buildup of a generalized distribution curve confirms the possibility to describe the polymerization processes within the framework of the mentioned model and allows one to predict the kinetics of MWD changes as the function of the initial monomer concentration c 0 and reac… Show more
“…Practical importance of DADMAC homopolymer and copolymer studies involving polymerization mechanism and kinetics, molecular characterization, and solution properties of this system have drawn great interest. Highly hygroscopic nature of PDADMAC causes difficulties in characterization polymerization reaction by chemical methods or isolation and gravimetrically . The electrostatic repulsion between the ion and the charged macroradical depend on the pH value of the medium and the concentrations of ionic species.…”
“…Practical importance of DADMAC homopolymer and copolymer studies involving polymerization mechanism and kinetics, molecular characterization, and solution properties of this system have drawn great interest. Highly hygroscopic nature of PDADMAC causes difficulties in characterization polymerization reaction by chemical methods or isolation and gravimetrically . The electrostatic repulsion between the ion and the charged macroradical depend on the pH value of the medium and the concentrations of ionic species.…”
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