Fourth international seminar on inclusion compounds

About the thermal decomposition of tetracyanocomplexes

“…For comparison, also other cyano-complexes [2] were used. Sotichiometric formulas are listed in Table 1 together with the numbering of the products used in this paper.…”

“…Morphological studies showed a changed situation after the formation of the new products prepared from clinoptilolite (CT) zeolites. After the inclusion reaction the original CT plates with very smooth surface were visibly impregnated in the SEM pictures [2] with newly formed little pits. Some amorphisation with the change in chemical composition and behaviour occurred [2] similarly as in [28].…”

“…After the inclusion reaction the original CT plates with very smooth surface were visibly impregnated in the SEM pictures [2] with newly formed little pits. Some amorphisation with the change in chemical composition and behaviour occurred [2] similarly as in [28]. Similar kinds of impregnation or preparation were found on the surface of the products by A. K. Galwey [32] in the case of new inorganic products and he held it for some kind of foaming structure.…”

“…In [2,[29][30][31]] the thermal stabilities of new inclusion compound combinations are dealt with. Morphological studies showed a changed situation after the formation of the new products prepared from clinoptilolite (CT) zeolites.…”

“…In a more precise form their general formula is comprising a whole series with a broad energetical variety of bonds existing between the elements, ligands and components forming the whole compound. The general formula is: [1,2,6], B= NH3, ethylenediamine, toluidine (o-, m-, p,), pyridine, dimethylamine, ammoniumalkalamine, 1,2-diaminopropane, dioxane .... [ 1,2,[7][8][9][10][11], G=HzO, C6H6, exhibiting different morphologies, thermal stabilities and properties. Little thermal effects may influence the formation of at least a part of weathered products.…”