Fourier Transform Spectroscopy of Carbonyl Sulfide from 4800 to 8000 cm−1and New Global Analysis of16O12C32S☆

Absolute Intensities Measurements in the ν4 + ν5 Band of 12C2H2: Analysis of Herman–Wallis Effects and Forbidden Transitions

“…The modulus square of the transition moments ͉R J (1-0)͉ 2 and ͉R J (2e-0)͉ 2 , calculated with Eqs. [8] and [7] using the values of the mixing coefficients obtained and assuming that ͉R vЈv u (1-0)͉ is equal to the observed value of the vibrational transition moment of the 4 ϩ 5 (⌺ u ϩ )-0(⌺ g ϩ ) band at m ϭ 0, are presented as dotted lines in Figs. 1 and 2, respectively.…”

“…Assuming that the upper level interacts with one of such ᐉ ϭ Ϯ1 levels, the modulus square of the transition moment associated to the 4 ϩ 5 (⌺ u ϩ )-0(⌺ g ϩ ) band, given in Eq. [8], can be written as:…”

FT Infrared Spectra of FCN from 1200 to 1800 cm−1 and from 2800 to 7000 cm−1 and Global Rovibrational Analysis of the Main Isotopomers

“…Such an analysis was first applied to the OCS molecule (18) in 1986. Complementary terms were introduced in the Hamiltonian in 1991 (19), and an improved version of this analysis was recently published (20). Details about the procedures can be found in those references.…”

Morphing the He–OCS intermolecular potential

“…33 The bound states reported here are for the isotopic species 4 34 with basis functions up to jϭ30 included in the calculations. The reduced mass of the complex was taken as 3.752 159 m u and the coupled equations propagated from R min ϭ2.2 Å to R max ϭ6.5 Å.…”