Fourier Thermal Analysis of the Eutectic Formed in Pb-Sn Alloys

Abstract

The effect of the presence of two different primary phases on the microstructural characteristics and solidification kinetics of Pb-Sn eutectic was analyzed using Fourier thermal analysis method (FTA) and microstructural characterization. Three Pb-Sn alloys, a hypoeutectic, an eutectic, and a hypereutectic alloy, were melted in an electric furnace under an argon atmosphere and poured into sand molds. Cooling curves were obtained and numerically processed using FTA. Microstructural observations of the probes indicate a lamellar morphology for the eutectic microconstituent of the hypereutectic alloy; the eutectic alloy shows the presence of both lamellar and anomalous eutectic and the hypoeutectic alloy shows only the presence of anomalous eutectic. FTA results indicate that in the case of the probes showing the presence of anomalous eutectic, there is a primary eutectic formed during recalescence at high undercooling and a secondary eutectic yielded at low undercooling at the eutectic plateau temperature. This result shows that the cause behind the observed differences in the eutectic morphologies of the experimental alloys lies on the nucleating ability of the primary phase available as a potential substrate for nucleation of the eutectic microconstituent.

An Evaluation of Combustion Kinetics for the Synthesis Reaction of the Reinforcing Phase During Casting Phase During Casting

“…In these papers, FTA has been used to determine the kinetics of gray cast iron solidification in the local region. Later, the FTA method has been successfully used to characterize the solidification process for various metal alloys, such as: aluminum-based materials [10][11][12][13][14][15], magnesium alloy [16], different Pb-Sb alloys [17], and for cast-composites [18]. As it has been proven in [19], the FTA method can also be used to analyze the kinetics of thermal decomposition of resin binders intended for use in molding sands.…”

Effect of Aging Treatment on Microstructural Evolution of Rapidly Solidified Eutectic Sn-Pb Alloy Powders

“…Gan et al reported the size effect of Sn-Pb microstructures on microdevices, and they indicated that stable microstructures are crucial in several applications [16]. The effect of the two primary phases on Sn-Pb microstructures was studied using thermal analysis method [17].…”