We use high precision lattice simulations to calculate the plaquette expectation value in three-dimensional SU(N c ) gauge theory for N c = 2, 3, 4, 5, 8. Using these results, we study the N c -dependence of the first non-perturbative coefficient in the weak-coupling expansion of hot QCD. We demonstrate that, in the limit of large N c , the functional form of the plaquette expectation value with ultraviolet divergences subtracted is 15.9(2) − 44(2)/N 2 c .