“…For example, the archetypical Schrock carbene (Cp) 2 33 , whereas X 2 Ti ¼ CH 2 (X ¼ H, F, Cl) species were isolated in low-temperature inert gas matrices 34,35 . At the same time, Ti alkylidenes with a higher coordination number, when Ti-based LUMO is further coordinated, can form stable molecules 22,23,[36][37][38][39] .…”