Abstract:In this study, antifouling membranes were prepared through dry wet‐phase inversion method. The incorporation of electrostatistically charged group of sulfonate cation exchange resins (SCER) into polyethersulfone membrane matrix attempts to give a synergistic combination of properties for bovine serum albumin (BSA) removal. The effect of different composition of SCER into the blend membranes were characterized using scanning electron microscopy, atomic force microscopy, porosimeter, attenuated total reflectance… Show more
“…The magnitudes of flux can be improved by decreasing membrane thickness. The selectivity of PVDF HPMs has been assessed by filtrating BSA solution [ 33 , 34 , 35 , 36 , 37 ]. As shown in Figure 6 B, the specimens from 1–10, 1–20, 2–10 and 2–20 exhibit a rejection ratio of ~80%.…”
In this work, poly (vinylidene fluoride) (PVDF) hierarchically porous membranes (HPMs) with isolated large pores and continuous narrow nano-pores have been fabricated from its blend with poly (methyl methacrylate) (PMMA) based on the combination of crystallization template with chemical or supercritical CO2 foaming. On the one hand, the decomposition of azodicarbonamide (ADC, chemical foaming agent) or the release of CO2 can produce isolated large pores. On the other hand, PMMA is expelled during the isothermal crystallization of PVDF in their miscible blend, yielding narrow nano-pores upon etching with a selective solvent. In the case of supercritical CO2, the attained PVDF HPMs fail to improve separation performance because of the compact wall of isolated-large-pore and consequent poor connectivity of hierarchical pores. In the case of ADC, the optimal HPM exhibits much higher flux (up to 20 times) without any loss of selectivity compared with the reference only with nano-pores. The enhanced permeability can be attributed to the shorter diffusion length and lower diffusion barrier from isolated large pores, while the comparable selectivity is determined by narrow nano-pores in THE matrix.
“…The magnitudes of flux can be improved by decreasing membrane thickness. The selectivity of PVDF HPMs has been assessed by filtrating BSA solution [ 33 , 34 , 35 , 36 , 37 ]. As shown in Figure 6 B, the specimens from 1–10, 1–20, 2–10 and 2–20 exhibit a rejection ratio of ~80%.…”
In this work, poly (vinylidene fluoride) (PVDF) hierarchically porous membranes (HPMs) with isolated large pores and continuous narrow nano-pores have been fabricated from its blend with poly (methyl methacrylate) (PMMA) based on the combination of crystallization template with chemical or supercritical CO2 foaming. On the one hand, the decomposition of azodicarbonamide (ADC, chemical foaming agent) or the release of CO2 can produce isolated large pores. On the other hand, PMMA is expelled during the isothermal crystallization of PVDF in their miscible blend, yielding narrow nano-pores upon etching with a selective solvent. In the case of supercritical CO2, the attained PVDF HPMs fail to improve separation performance because of the compact wall of isolated-large-pore and consequent poor connectivity of hierarchical pores. In the case of ADC, the optimal HPM exhibits much higher flux (up to 20 times) without any loss of selectivity compared with the reference only with nano-pores. The enhanced permeability can be attributed to the shorter diffusion length and lower diffusion barrier from isolated large pores, while the comparable selectivity is determined by narrow nano-pores in THE matrix.
“…The pure and PVDF‐B 4 C photocatalytic membranes using the phase inversion 23,24 . In brief, a predetermined amount of B 4 C nanoparticle (NP) was dispersed in DMAC using the probe ultrasonicator (KS‐250SDN) for 15 min.…”
Section: Methodsmentioning
confidence: 99%
“…The pure and PVDF-B 4 C photocatalytic membranes using the phase inversion. 23,24 In brief, a predetermined amount of B 4 C nanoparticle (NP) was dispersed in DMAC using the probe ultrasonicator (KS-250SDN) for 15 min. Then, PVDF powder was added into the dispersed solution under agitation of 350 rpm for 16 h. For pure membrane, PVDF powder was added in DMAC under agitation of 350 rpm for 16 h. Table 1 presents the composition of membrane dope solution.…”
Section: Synthesis Of Pure and Pvdf-b 4 C Mixed Matrix Membranesmentioning
In this work, polyvinylidene fluoride-boron carbide mixed matrix membranes were synthesized via phase inversion method. The synthesized membranes were characterized using field emission scanning electron microscopy, X-ray diffraction spectroscopy, energy dispersive spectroscopy, porosity, and contact angle. The mixed matrix membranes (0-5 wt.% of boron carbide) were tested for ultrafiltration of bovine serum albumin solution and photodegradation property using rhodamine B and methylene blue dyes. The morphological images reveal the existence of boron carbide particles on the surface of the membranes. Upon introduction of B 4 C particles, the performance of the membranes was improved: permeate flux increases from 163.13 to 351.15 L/m 2 h; bovine serum albumin rejection increased from 77.1% to 99.1%; relative flux reduction decreased from 45.58% to 16.06%; flux recovery ratio increased from 61.71% to 98.42%. Furthermore, maximum photodegradation yield was observed for membranes with 4 wt.% boron carbide particles with degradation efficiency of 96.7% and 96% for rhodamine B and methylene blue dyes, respectively. Furthermore, the rate constant of the optimum membrane was higher than the pristine membrane (about 2.05 and 2.26 times higher for rhodamine B and methylene blue dyes, respectively). Indeed, the mixed matrix membranes present a great prospect for the photodegradation of organic dyes.
“…This is because functionalized membranes form strong bonds with the components and are less vulnerable to heat degradation. Membrane hydrophilicity plays an important role in fouling resistance, and previous research has suggested that organic components such as HA and protein usually exhibit lower fouling tendencies when using a more hydrophilic surface [40,41]. The contact angle of the prepared membranes is shown in Table 3.…”
In the present work, a highly efficient mixed matrix membrane (MMM) for humic acid (HA) removal was developed. Multiwalled carbon nanotubes (MWCNTs) were functionalized in the presence of 3-methacryloxypropyl trimethoxysilane using the co-condensation method and were subsequently loaded with TiO2 (prepared via the sol–gel route). The as-prepared material was then incorporated into a PES polymer solution to prepare a fMWCNT-TiO2/PES hybrid membrane via non-solvent induced phase inversion. The microstructure of the membrane was characterized using Fourier transform infrared spectroscopy, atomic force microscopy, scanning electron microscopy, water contact angle, thickness, porosity, and pore size. The fMWCNT-TiO2/PES hybrid membrane was tested for the removal of HA and antifouling performance. The results show that the surface hydrophilicity of the membranes was greatly improved upon the addition of the fMWCNT-TiO2 particles. The results show that 92% of HA was effectively removed after 1 h of filtration. In comparison with pristine membrane, the incorporation of fMWCNT-TiO2 nanoparticles led to enhanced pure water flux (99.05 L/m2 h), permeate flux (62.01 L/m2 h), higher HA rejection (92%), and antifouling improvement (RFR: 37.40%, FRR: 86.02%). Thus, the fMWCNT-TiO2/PES hybrid membrane is considered to be a great potential membrane for the improvement of ultrafiltration membranes.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.