Imperfection of a reaction-diffusion system is investigated. This imperfection causes modification of Fick's equation. We provide imperfection of diffusion fluxes on the basis of a chemical reaction model of unimolecular and bimolecular processes with two intermediate substances. We demonstrate that allowing for imperfection of diffusion processes leads to introducing the spatial derivatives of fourth order in the evolution equations for concentrations of intermediate substances. It is important that dissipative structures including oscillations can be formed in the system due to the availability of these derivatives in the evolution equations. It is proved that the necessary condition of forming the dissipative structures can appear due to imperfection of diffusion processes in the systems considered. It is shown by linear analysis that concentration of the intermediate substance near a stationary state can exhibit oscillatory behavior under certain conditions. Phase-plane portrait peculiarities of a nonlinear system are investigated at different values of the initial parameters. It is shown by numerical simulation that dependence of concentrations of the intermediate substances has a quasi-periodical character.