2011
DOI: 10.1021/cg201163v
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Formation of Inert Bi2Se3(0001) Cleaved Surface

Abstract: A high quality inclusion-free Bi2Se3 crystal has been grown by the Bridgman method with the use of a rotating heat field. A large-area atomically flat Bi2Se3(0001) surface of excellent crystallographic quality has been formed by cleavage. Chemical and microstructural properties of the surface have been evaluated with reflection high-energy electron diffraction, atomic force microscopy (AFM), scanning tunneling microscopy (STM), spectroscopic ellipsometry, and X-ray photoelectron spectroscopy. There was no Bi2S… Show more

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Cited by 118 publications
(73 citation statements)
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“…We did not observe any states at the Fermi level related to the conduction band in the spectra using a wide range of photon energies including 21.2 eV. The surface stability can be explained by the low concentration of surface defects in our samples grown by modified Bridgman method [42,43]. The energy shift of the Dirac point toward the Fermi level with time can be related to the adsorption of the residual oxygen-contained gases at the surface, in contrast to the case of CO adsorption which leads to a shift of the Dirac point in the opposite direction [31].…”
Section: Electronic and Spin Structurementioning
confidence: 73%
“…We did not observe any states at the Fermi level related to the conduction band in the spectra using a wide range of photon energies including 21.2 eV. The surface stability can be explained by the low concentration of surface defects in our samples grown by modified Bridgman method [42,43]. The energy shift of the Dirac point toward the Fermi level with time can be related to the adsorption of the residual oxygen-contained gases at the surface, in contrast to the case of CO adsorption which leads to a shift of the Dirac point in the opposite direction [31].…”
Section: Electronic and Spin Structurementioning
confidence: 73%
“…An energetically favored heterostructure, Bi2Se3 (1×1)/Ag (1×1), with the selenium termination is adopted [37][38][39]. The ion-electron, electron-electron and van der Waals (vdW) interactions between Ag and Bi2Se3 are included in our model implemented in the Vienna ab initio simulation package (VASP) [24,40,41].…”
mentioning
confidence: 99%
“…Prior any experimental measurement, powders were compacted into relatively thin pellets by cold pressing under Ar atmosphere. The depth profiling of Y 2 O 3 samples was performed by alternating Ar + ion sputtering and bombardment with XPS data acquisition and analysis [34][35][36]. Energy of Ar + ions, current density, and angle of sputtering-induced erosion were set equal to 1.05 keV, 4-5 A cm −2 , and 45 • respectively.…”
Section: Experimental Methodologymentioning
confidence: 99%