1990
DOI: 10.1103/physrevb.41.9607
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Formation of an anisotropic energy gap in the valence-fluctuating system of CeNiSn

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Cited by 330 publications
(143 citation statements)
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“…Furthermore, the electrical resistivity, ρ(T ), of valence fluctuating systems typically shows a Fermi liquid-like quadratic temperature dependence at low temperature and a shoulder in ρ(T ) at high temperatures. [4,5,6,7] The element Yb has an ambivalent character in a number of metallic compounds, resulting in an intermediate-valence state consisting of a temporal admixture of Yb 3+ (4f 13 ) and Yb 2+ (4f 14 ). [8] In particular, Yb compounds are also of interest because the trivalent Yb ion can be thought of as the 4f hole counterpart of the trivalent Ce ion, which has one electron in its 4f shell.…”
Section: Introductionmentioning
confidence: 99%
“…Furthermore, the electrical resistivity, ρ(T ), of valence fluctuating systems typically shows a Fermi liquid-like quadratic temperature dependence at low temperature and a shoulder in ρ(T ) at high temperatures. [4,5,6,7] The element Yb has an ambivalent character in a number of metallic compounds, resulting in an intermediate-valence state consisting of a temporal admixture of Yb 3+ (4f 13 ) and Yb 2+ (4f 14 ). [8] In particular, Yb compounds are also of interest because the trivalent Yb ion can be thought of as the 4f hole counterpart of the trivalent Ce ion, which has one electron in its 4f shell.…”
Section: Introductionmentioning
confidence: 99%
“…Other 4f compounds with insulating ground states are TmSe (A = 2 meV) [3], SmB6 0925-8388/92/$5.00 © 1992-Elsevier Sequoia. All rights reserved (A=3-4 meV) [41, YDB12 (A=6 meV) [5], CeFe4P12 (A=130 meV) [61, CeNiSn (A=0.5 meV) [7] and CeRhSb (A=0.4 meV) [8]. Some of these compounds are intermediate valence.…”
Section: Introductionmentioning
confidence: 99%
“…Being much smaller than usual, doors are opened for the observation of phenomena usually unobservable. At high temperatures these systems can be described in terms of localized moments [27][28][29][30][31]. If in the HF state any low-temperature magnetic ordering is observed, it usually is antiferromagnetic.…”
Section: Heavy Fermionsmentioning
confidence: 99%
“…The outcome of the charge transfer considerations must be treated as an extra restriction for the used model. To satisfy photon emission experiments [30,40], we do not start with an empty f-level but with a single occupied f-level having a contact potential (without charge transfer and without hybridization) ¢o =/tA-/ta of 2eV. Charge transfer causes the effective contact potential to change into (still without hybridization) 4) = ¢o -PAnn.…”
Section: Charge Transfer Effectsmentioning
confidence: 99%