Removal of carbon dioxide (CO 2 ) from natural gas is of importance because the existence of CO 2 in natural gas increases the cost of the sweetening process. In recent years, membrane technology has emerged as an attractive alternative in separating CO 2 from CH 4 due to its economical, efficient, and environmentally-friendly process. Here, we review the different types of membranes used in CO 2 /CH 4 gas separation. Zeolitic imidazolate frameworks (ZIFs) membranes are emphasized and ZIF-8 membranes are selected for further discussion due to their remarkable properties, including high chemical and thermal stability, facile and controllable pore apertures, and high CO 2 permeance. Different types of methods used for the synthesis of ZIF membranes and the challenges encountered in the growth of the membrane are summarized. Potential use of microwave technology in fabricating a continuous and low-defects ZIF membrane within a short period of time are discussed and highlighted. In conclusion, future direction and perspectives are indicated.