Formation Constants of Transition Metal Mixed Ligand Ternary Complexes with Biologically Significant Ligands
Abstract:Coordination of ternary complexes of biologically active ligands with transition metals were investigated in aqueous media at 37±1 °C under ionic strength I = 0.1 M NaNO 3. Amino acid asparagine (primary ligand =A) and nucleic acid thiouracil (secondary ligand=B) were applied for complex formation with Cu(II), Ni(II), Zn(II) and Co(II) in aqueous solution (1:1:1). The plausible equilibria have been deduced on the basis of speciation curves obtained through BEST computer program and species are also presented a… Show more
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