Abstract:Photochemical reactions of organic sulfur compounds (CH 3 SCH 3 , C 2 H 5 SCH 3 , and C 2 H 5 SC 2 H 5 ) _ chlorine atom complexes have been studied using a combined pulse radiolysis _ laser flash photolysis technique. Excitation of all complexes has resulted in photobleaching with a similar quantum yield (0.37 ± 0.07), independent of solvent polarities and concentration of solutes. The results were compared with previous studies of the analogous dimethyl sulfoxide (DMSO) _ Cl complexes. It is concluded that t… Show more
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