Formation and phase control of Co–Gd alloy films by molten salt electrochemical process

Kubota, Tadashi; Iida, Takahisa; Ito, Yasuhiko

doi:10.1016/j.jallcom.2004.02.041

Cited by 15 publications

(9 citation statements)

References 13 publications

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“…Even if other authors propose also cobalt [21], classically the cathode material can be nickel or copper, since these metals react easily and rapidly with Ln to give intermetallic compounds identified on the binary diagrams [22] and are more easily available than Co. A typical example of binary diagram is shown for the copper-neodymium system in Fig. 4.…”

Section: Reactive Cathode Methodsmentioning

confidence: 99%

Lanthanides extraction processes in molten fluoride media: Application to nuclear spent fuel reprocessing

Taxil

Massot

Nourry

et al. 2009

Journal of Fluorine Chemistry

104

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Section: Reactive Cathode Methodsmentioning

confidence: 99%

Lanthanides extraction processes in molten fluoride media: Application to nuclear spent fuel reprocessing

Taxil

Massot

Nourry

et al. 2009

Journal of Fluorine Chemistry

104

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“…The electrochemical formation of Gd-Co alloys was investigated in a molten LiCl-KCl-GdCl 3 system at 450 • C. CoGd 3 film was formed on Co substrate by cathodic electrolysis [153].…”

Section: Groupmentioning

confidence: 99%

Electrodeposition of metals from non-aqueous solutions

Simka

Puszczyk

Nawrat

2009

Electrochimica Acta

271

161

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“…Kubota et al [7] observed the formation of different alloys Co 3 Gd, Co 2 Gd and Co 7 Gd 2 by reduction of Gd(III) in the LiCl-KCl eutectic on a Co electrode at fixed potential.…”

Section: Introductionmentioning

confidence: 99%

Electrochemical reduction of Gd(III) and Nd(III) on reactive cathode material in molten fluoride media

et al. 2008

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The electrochemical reduction of two lanthanides (neodymium Nd and gadolinium Gd) was investigated in the 800-950°C temperature range on nickel and copper electrodes. These materials react with lanthanides (Ln) to form intermetallic compounds. The formation mechanism of the alloys was determined by coupling electrochemical techniques and Scanning Electron Microscopy (SEM) after electrolyses runs; this also allowed the identification of the binary compounds formed. In addition, from the electrochemical results, we calculated the Gibbs energies of Nd/Ni, Gd/Ni, Gd/Cu and Nd/Cu.

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Formation and phase control of Co–Gd alloy films by molten salt electrochemical process

Cited by 15 publications

References 13 publications

Lanthanides extraction processes in molten fluoride media: Application to nuclear spent fuel reprocessing

Lanthanides extraction processes in molten fluoride media: Application to nuclear spent fuel reprocessing

Electrodeposition of metals from non-aqueous solutions

Electrochemical reduction of Gd(III) and Nd(III) on reactive cathode material in molten fluoride media

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