Formate dehydrogenase activity by a Cu(<scp>ii</scp>)-based molecular catalyst and deciphering the mechanism using DFT studies

Mishra, Aman; Srivastava, Diship; Raj, Dev; Patra, Niladri; Padhi, Sumanta Kumar

doi:10.1039/d3dt03023g

Dalton Trans.

2024

DOI: 10.1039/d3dt03023g

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Formate dehydrogenase activity by a Cu(ii)-based molecular catalyst and deciphering the mechanism using DFT studies

Aman Mishra,

Diship Srivastava,

Dev Raj

et al.

Abstract: A copper catalyst [Cu(N3Q3)Cl]Cl (N3Q3 = N,N-bis(quinolin-8-ylmethyl)quinolin-8-amine) has been employed for the dehydrogenation of formic acid. The thermodynamics and the kinetics have been depicted, and a mechanism deduced using DFT studies.

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Advances in the Homogeneously Catalyzed Hydrogen Production from Biomass Derived Feedstocks: A Review

Fasolini,

Martelli,

Piazzi

et al. 2024

ChemCatChem

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Biomass‐derived feedstocks for hydrogen production are crucial as an alternative to fossil fuel especially in those areas where green electricity and clean water are scarce. In this framework the transformation of simple (formic acid, alcohols) and more complex (polyalcohols, sugars and cellulose) bio‐derivatives in pure hydrogen is recognized as a promising approach. Parallel to great effort in heterogeneous catalysis, milder molecular systems represent a more selective eye for alternative solutions and mechanistic insights. In the present review the introduction summarizes the challenges in the catalytic utilization of biomass‐derived feedstocks, followed by the advances in homogeneously catalyzed hydrogen production from different substrates which will cover formic acid, with oustanding efficiency with noble metals and promising results with earth abundant ones and alcohols and polyalcohols, with particular emphasis to the development of heterogenized systems, ligand assisted catalysts and bi‐catalytic synergistic solutions which allow to avoid base and to promote catalyst stability and recyclability. In the last part, description of hydrogen production from more complex substrates, such as sugars and cellulose, will show the role of molecular complexes in main and side reactions. Critical comments on the reported advances are provided along the whole discussion.

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Advances in the Homogeneously Catalyzed Hydrogen Production from Biomass Derived Feedstocks: A Review

Fasolini,

Martelli,

Piazzi

et al. 2024

ChemCatChem

View full text Add to dashboard Cite

show abstract

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Formate dehydrogenase activity by a Cu(ii)-based molecular catalyst and deciphering the mechanism using DFT studies

Abstract: A copper catalyst [Cu(N3Q3)Cl]Cl (N3Q3 = N,N-bis(quinolin-8-ylmethyl)quinolin-8-amine) has been employed for the dehydrogenation of formic acid. The thermodynamics and the kinetics have been depicted, and a mechanism deduced using DFT studies.

Cited by 1 publication

References 60 publications

Advances in the Homogeneously Catalyzed Hydrogen Production from Biomass Derived Feedstocks: A Review

Advances in the Homogeneously Catalyzed Hydrogen Production from Biomass Derived Feedstocks: A Review

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