Formaldehyde sensor using non-dispersive UV spectroscopy at 340nm

Abstract

Formaldehyde is a volatile organic compound that exists as a gas at room temperature. It is hazardous to human health causing irritation of the eyes, nose and throat, headaches, limited pulmonary function and is a potential human carcinogen. Sources include incomplete combustion, numerous modern building materials and vehicle fumes. Here we describe a simple method for detecting formaldehyde using low resolution non-dispersive UV absorption spectroscopy for the first time. A two channel system has been developed, making use of a strong absorption peak at 339nm and a neighbouring region of negligible absorption at 336nm as a reference. Using a modulated UV LED as a light source and narrowband filters to select the desired spectral bands, a simple detection system was constructed that was specifically targeted at formaldehyde. A minimum detectable absorbance of 4.5 × 10 -5 AU was estimated (as ∆I/I 0 ), corresponding to a limit of detection of approximately 6.6 ppm for a 195mm gas cell, with a response time of 20s. However, thermallyinduced drift in the LED spectral output caused this to deteriorate over longer time periods to around 30 ppm or 2 × 10 -4 AU.