Forensic analytical aspects of homemade explosives containing grocery powders and hydrogen peroxide

Abstract

Homemade explosives become a significant challenge for forensic scientists and investigators. In addition to well-known materials such as acetone peroxide trimer, black powder, or lead azides, perpetrators often produce more exotic and less recognized Homemade Explosives (HMEs). Mixtures of hydrogen peroxide with liquid fuels are widely acknowledged as powerful explosives. Interestingly, similar explosive properties are found in mixtures of numerous solid materials with H2O2. Notably, powdered groceries, such as coffee, tea, grounded spices, and flour, are particularly interesting to pyrotechnics enthusiasts due to their easy production using accessible precursors, which do not attract the attention of security agencies. H2O2-based HMEs may become a dangerous component of improvised explosive devices for terrorists and ordinary offenders. For the four most powerful mixtures—HMEs based on coffee, tea, paprika, and turmeric—molecular markers useful for identification using the GC–MS technique have been proposed. Furthermore, the observed time-dependent changes in mixtures of H2O2 with these food products were studied and evaluated as a potential method for assessing the age of the evidence and reconstructing timelines of crimes. The paper also discusses the usefulness of FT-IR spectroscopy for identifying H2O2-based HMEs.