Force balance in systems of spherical polyelectrolytes

Enos, B.; McQuarrie, Donald A.; Colonomos, Peter

doi:10.1016/0021-9797(75)90202-7

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1976

1987

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“…Equations more general than eq 2 have been developed. [19][20][21] The interaction potential given by eq 2 appears at first glance to be considerably softer than that given in eq 1. It is shown below that for the purposes of studying the phase transition eq 2 can be approximated by eq 1 by choosing an effective hard-sphere diameter *.…”

Section: Theorymentioning

confidence: 99%

A semiempirical model for the phase transition in polystyrene latexes

Brenner¹

1976

J. Phys. Chem.

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A simple model for the phase transition in polystyrene latexes has been developed. The model assumes a priori that the transition is fundamentally caused by repulsion between the spherical latex particles, i.e., it is fundamentally hard sphere in nature, but that the hard sphere diameter of the polystyrene particles is in fact ionic-strength dependent. The resulting volume fraction vs. salt concentration phase diagram is in qualitative accord with the experimental phase diagram of Hachisu and co-workers.

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Section: Theorymentioning

confidence: 99%