Flux Synthesis of Alkaline-Earth Lanthanide Borates as Potential Nuclear Waste Forms
Gregory Morrison,
Adrian T. Hines,
Virginia G. Jones
et al.
Abstract:Neodymium is typically considered the best surrogate for trivalent americium and can be used to identify Am 3+ containing materials that are likely to form. We have explored the alkaline-earth lanthanide borate phase space using alkaline-earth halide/carbonate fluxes. This resulted in the synthesis of new compounds AE 5 Ln-(BO 3 ) 4 X (AE = Ca, Sr; Ln = Pr, Nd, Eu, Tb; X = Cl, Br) and AE 3 Ln 2 (BO 3 ) 4 (AE = Sr, Ba; Ln = Pr, Nd) as well as the synthesis of two compounds of Ba 8 Ln 2 (BO 3 ) 6 (B 2 O 5 ) (Ln … Show more
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