GUT monopoles captured by the Sun's gravitation are expected to catalyze proton decays via the Callan-Rubakov process. In this scenario, protons, which initially decay into pions, will ultimately produce ν e , ν µ and νµ . After undergoing neutrino oscillation, all neutrino species appear when they arrive at the Earth, and can be detected by a 50,000 metric ton water Cherenkov detector, Super-Kamiokande (SK). A search for low energy neutrinos in the electron total energy range from 19 to 55 MeV was carried out with SK and gives a monopole flux limit of F M (σ 0 /1mb) < 6.3 × 10 −24 (β M /10 −3 ) 2 cm −2 s −1 sr −1 at 90% C.L., where β M is the monopole velocity in units of the speed of light and σ 0 is the catalysis cross section at β M = 1. The obtained limit is more than eight orders of magnitude more stringent than the current best cosmic-ray supermassive monopole flux limit, F M < 1 × 10 −15 cm −2 s −1 sr −1 for β M < 10 −3 and also two orders of magnitude lower than the result of the Kamiokande experiment, which used a similar detection method.