Fluorous-phase soluble rhodium complexes: X-ray structure of [RhCl(CO)(P(C2H4C6F13)3 )2]

Prediction of fluorophilicity of organic and transition metal compounds using molecular surface areas

“…Fig. 1 shows a superimposition of the X-ray and Lanl2DZ structures, which clearly shows how the optimised structure reproduces the characteristic shape of the complex, described by the authors as resembling ''rugby posts'' for four of the six fluorous chains, with the remaining two chains approximately perpendicular to these [24]. Furthermore, this figure also shows how the experimental problem of positional disorder, resulting from thermal motion of the flexible fluorous chains, is resolved in theoretical optimisation.…”

Coordination chemistry of perfluoroalkylated phosphorus(III) ligands

“…Turning now to the palladium(II) complexes, 31 [27,28], (27) and (29) [29] have been described previously. trans-[IrCl(CO)L 2 ] (L = L1, L2, L3; 32,33,34) are prepared by carbonylation of the product from the cleavage of [IrCl(COD)] 2 with the respective phosphines; trans-[IrCl(CO)(L3) 2 ] (34) has been described previously [28].…”

Solution Thermochemical Study of a Fluorous Tertiary Phosphine Ligand in Rhodium and Ruthenium Systems

“…Rh(PR f3 ) 2 (CO)Cl (6). In a manner analogous to that for 4 , 6 was isolated from 1 and the phosphine as a yellow microcrystalline solid in 90% yield. 31 P NMR (THF- d 8 , 25 °C): δ 23.54 (d, J Rh-P = 121 Hz).…”