Fluorous Organometallic Chemistry

Hope, Eric G.; Simayi, Rena; Stuart, Alison M.

doi:10.1007/3418_2015_91

Cited by 3 publications

(4 citation statements)

References 142 publications

(107 reference statements)

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Fluorous technologies in catalysis and green chemistry, including fluorous biphasic catalysis and fluorous monophasic catalysis, have shown broad applications because of the facile separation of the system. − …”

Section: Homogeneous Catalysis and Heterogeneous Separationmentioning

confidence: 99%

“…The fluorous–fluorous interaction is another weak interaction that can be used to immobilize homogeneous catalysts. , In 2012, Cai’s group developed fluorous-silica-gel-immobilized perfluoro-tagged molecular NHC-Pd catalyst 259 via fluorous–fluorous interactions (Scheme ). The heterogeneous catalyst was applied in the Suzuki reaction, and through a filtration process, catalyst 259 could be easily recovered and reused three times without an apparent loss in activity.…”

Section: Immobilized (Heterogenized) Nhc Complex Catalystmentioning

confidence: 99%

“…Therefore, SBA-15 has also often been exploited as a catalyst support. In 2013, Hou and co-workers developed an SBA-15-supported pyrimidine-substituted NHC-Ir catalyst, 258 and this heterogenized catalyst (198) was applied in the N-alkylation of amines with alcohols and the β-alkylation of secondary alcohols with primary alcohols (Scheme 77). It is worth noticing that a synergistic effect existed between the organometallic part and the support part of SBA-15, which led to an improved catalytic activity compared to that of the homogeneous counterpart.…”

Section: Chemical Reviewsmentioning

confidence: 99%

See 2 more Smart Citations

Reusable N-Heterocyclic Carbene Complex Catalysts and Beyond: A Perspective on Recycling Strategies

et al. 2018

View full text Add to dashboard Cite

With the continuous development of N-heterocyclic carbene (NHC) chemistry during the past decade, NHC metal complexes have gained wide applications in the research field of organometallic catalysis. The recycling and reuse of NHC metal complexes, which have undergone continuous expansion and diversification, can enhance their catalytic performance, extend their range of application, and afford new routes to green chemistry. Taking NHC metal complex catalysts as the main topic, this review intends to present a comprehensive study of recycling strategies of organometallic catalysts. By an elaborative summarization and classification of recycling strategies, a clear picture of all available of recycling strategies for organometallic catalysts is presented and the advantages and disadvantages of various recycling strategies for specific reactions are discussed in detail. This review is written with the hope of serving as a modest spur to induce other scientists' further contributions in the fields of catalyst recycling and sustainable catalysis.

show abstract

Section: Homogeneous Catalysis and Heterogeneous Separationmentioning

confidence: 99%

Section: Immobilized (Heterogenized) Nhc Complex Catalystmentioning

confidence: 99%

Section: Chemical Reviewsmentioning

confidence: 99%

See 1 more Smart Citation

Reusable N-Heterocyclic Carbene Complex Catalysts and Beyond: A Perspective on Recycling Strategies

et al. 2018

View full text Add to dashboard Cite

show abstract

“…In general, from the very onset of academic and industrial research on NHC complexes, studies of perfluoroalkyl-or perfluoralkylene containing NHC derivatives have been communicated regularly, but only sparsely with regard to this special area [34][35][36][37][38][39][40][41][42][43][44][45][46].…”

Section: Introductionmentioning

confidence: 99%

A Fluoroponytailed NHC–Silver Complex Formed from Vinylimidazolium/AgNO3 under Aqueous–Ammoniacal Conditions

et al. 2022

View full text Add to dashboard Cite

3-(1H,1H,2H,2H-Perfluorooctyl)-1-vinylimidazolium chloride [2126844–17–3], a strong fluorosurfactant with remarkably high solubility in water, was expediently converted into the respective doubly NHC-complexed silver salt with nitrate as counter ion in quantitative yield. Due to its vinyl substituents, [bis(3-(1H,1H,2H,2H-perfluorooctyl)-1-vinylimidazol-2-ylidene)silver(I)] nitrate, Ag(FNHC)2NO3, represents a polymerizable N-heterocyclic carbene transfer reagent, thus potentially offering simple and robust access to coordination polymers with crosslinking metal bridges. The compound was characterized by infrared and NMR spectroscopy, mass spectrometry as well as elemental analysis, and supplemented by X-ray single-crystal structure determination. It crystallizes in the monoclinic crystal system in the space group P21/c. With 173.3°, the geometry of the Ag-carbene bridge deviates slightly from linearity. The disordered perfluoroalkyl side chains exhibit a helical conformation.

show abstract

ChemInform Abstract: Fluorous Organometallic Chemistry

2016

View full text Add to dashboard Cite

show abstract

Fluorous Organometallic Chemistry

Abstract: The synthesis, characterisation and application of organometallic complexes functionalised with fluorous substituents are reviewed.

Cited by 3 publications

References 142 publications

Reusable N-Heterocyclic Carbene Complex Catalysts and Beyond: A Perspective on Recycling Strategies

Reusable N-Heterocyclic Carbene Complex Catalysts and Beyond: A Perspective on Recycling Strategies

A Fluoroponytailed NHC–Silver Complex Formed from Vinylimidazolium/AgNO3 under Aqueous–Ammoniacal Conditions

ChemInform Abstract: Fluorous Organometallic Chemistry

Contact Info

Product

Resources

About