Fluoropolymer-based architectural textiles: production, processing, and characterization

Sonnendecker, Anya; Viljoen, David; Améduri, Bruno; Crouse, Philip

doi:10.1016/b978-0-12-821873-0.00010-2

Cited by 5 publications

(3 citation statements)

References 34 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…When copolymerizing VDF with HFP, two behaviors of polymers can be obtained: thermoplastic and elastomeric poly(VDF- co -HFP). If the HFP content in the poly(VDF- co -HFP) copolymer is above 15 mol%, soft amorphous products are obtained [ 1 , 49 , 50 , 51 , 52 ].…”

Section: Resultsmentioning

confidence: 99%

Are (Co)Polymers of 1,1,3,3,3-Pentafluoropropene Possible?

et al. 2023

View full text Add to dashboard Cite

The copolymerization and terpolymerization of 1,1,3,3,3-pentafluoropropene (PFP) with various combinations of fluorinated and hydrogenated comonomers were investigated. The chosen fluoromonomers were vinylidene fluoride (VDF), 3,3,3-trifluoropropene (TFP), hexafluoropropene (HFP), perfluoromethylvinyl ether (PMVE), chlorotrifluoroethylene (CTFE) and tert-butyl-2-trifluoromethacrylate (MAF-TBE), while the hydrocarbon comonomers were vinylene carbonate (VCA), ethyl vinyl ether (EVE) and 3-isopropenyl-α,α-dimethylbenzyl isocyanate (m-TMI). Copolymers of PFP with non-homopolymerizable monomers (HFP, PMVE and MAF-TBE) led to quite low yields, while the introduction of VDF enabled the synthesis of poly(PFP-ter-VDF-ter-M3) terpolymers with improved yields. PFP does not homopolymerize and delays the copolymerizations. All polymers were either amorphous fluoroelastomers or fluorothermoplastics with glass transition temperatures ranging from −56 °C to +59 °C, and they exhibited good thermal stability in air.

show abstract

Section: Resultsmentioning

confidence: 99%

Are (Co)Polymers of 1,1,3,3,3-Pentafluoropropene Possible?

et al. 2023

View full text Add to dashboard Cite

show abstract

“…Fluorinated polyolefin materials have widespread utility due to their remarkable chemical, physical, electrical, and mechanical properties, mostly arising from the high polarity and strength of C–F bonds. 1–7 Currently, numerous fluorinated polyolefin materials (Scheme 1a), such as poly(tetrafluoroethylene) (PTFE), fluorinated ethylene propylene (FEP), poly(ethylene- co -tetrafluoroethylene) (ETFE) and poly(vinylidine difluoride) (PVDF), are manufactured through a radical process. 8,9 Compared to perfluorinated polyolefins, partially fluorinated polyolefins have attracted a lot of attention due to their better processability and safety.…”

Section: Introductionmentioning

confidence: 99%

Synthesis of partially fluorinated polyolefins via copolymerization of ethylene with fluorinated norbornene-based comonomers

Meng,

Liao,

et al. 2024

Polym. Chem.

View full text Add to dashboard Cite

show abstract

“…Textile roofing solutions have proven to be a promising innovation, providing protection and safety for people and withstanding difficult climatic conditions [1,2]. Specially treated textiles and fabrics are increasingly being used to meet the challenges posed by heavy rainfall, extreme heat, or high winds in different climatic environments [3,4]. The requirements for textile roofs are many and varied.…”

Section: Introductionmentioning

confidence: 99%