2016
DOI: 10.1149/ma2016-02/3/498
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Fluorolytic Sol-Gel Preparation of a Composite of Lithium Fluoride and Iron Difluoride As a Positive Electrode Material for Lithium Secondary Batteries

Abstract: A composite of lithium fluoride (LiF) and iron difluoride (FeF2) has been prepared by the reaction of the corresponding metal acetates and anhydrous hydrogen fluoride in ethanol in view of its application as a positive electrode material for lithium secondary batteries. The obtained LiF/FeF2 composite shows weak XRD peaks assigned to LiF and FeF2, and crystallite size is estimated to be 12 nm by the Scherrer’s equation. The composite powder exhibits a high N­2-adsorption capacity with adsorption-desorption loo… Show more

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