“…The amount of alkali content in the electrolyte for the oxidation of magnesium alloys can be reduced by using various additives [29]. In addition, there is an opinion that the addition of fluoride-containing compounds to the electrolyte significantly improves the quality of the oxide layer [21,[30][31][32][33].…”
“…The amount of alkali content in the electrolyte for the oxidation of magnesium alloys can be reduced by using various additives [29]. In addition, there is an opinion that the addition of fluoride-containing compounds to the electrolyte significantly improves the quality of the oxide layer [21,[30][31][32][33].…”
“…Most popular electrolytes used for forming coatings on magnesium and its alloys are water solutions of sodium and potassium hydroxide, sodium silicate, sodium phosphate, and sodium aluminates [8][9][10][11][12]. Recent studies have shown that the addition of fluoride in these electrolytes can promote the formation of protective coatings with increased resistance to pitting corrosion and wear resistance [13][14][15].…”
“…플라즈마 전해산화 피막의 형 성 거동 및 산화피막의 특성은 전해질의 화학적 조 성, 농도 및 온도, 인가전류의 크기 및 형태 등의 조건에 영향을 받는다. 그 중, 전해액의 조성 및 농 도는 피막의 형성 및 특성에 결정적인 역할을 하며, 규산염 [7][8][9], 인산염 [10][11][12], 불소 [13][14][15][16] 및 산화티 타늄 [17], 산화세륨 [18], 이산화규소 [19,20] …”
The structure of plasma electrolytic oxidation (PEO) coatings was investigated as a function of NaOH concentration in 0.06 M Na 2 SiO 3 + 0.06 M Na 3 PO 4 solution by using SEM and epoxy replica method. The PEO film was formed on AZ31 Mg alloy by the application of anodic pulse current with 0.2 ms width and its formation behavior was studied by voltage-time curves during the formation of PEO films. It was found that the addition of NaOH into PO 4 3-and SiO 3 2-containing aqueous solution causes a decrease in the PEO film formation voltage, suggesting that dielectric breakdown of the PEO becomes easier with increasing OH -ion concentration in the solution. With increasing OH -ion concentration, thickness of the PEO film increased and surface roughness decreased. The size of pores formed in the PEO layer became smaller and the number of cracks in the PEO layer increased with increasing OH -ion concentration. Based on the experimental results obtained in the work, it is suggested that OH -ions in the solution can contribute not only to the dielectric breakdown but also to the formation of PEO films in the presence of PO 4 3-and SiO 3 2-ions in the solution.
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