Fluoride-Based Deep Eutectic Solvents with Amide Dual-Hydrogen-Bond Donors
Hiroki Yamamoto,
Mineyuki Hattori,
Kenji Ito
et al.
Abstract:Developing F − -containing electrolytes is crucial for electrochemical and chemical fluorination. However, balancing the F − concentration and electrochemical stability of the electrolytes remains a challenge. In this study, fluoride-based deep eutectic solvents (F-DESs) were obtained by using amide hydrogen-bond donors (HBDs) containing dual N−H bonds. The obtained F-DES, [TMA]F•3.5[1,3-DMU], was prepared by facilely mixing solid compounds of tetramethylammonium fluoride ([TMA]F) and 1,3-dimethylurea (1,3-DMU… Show more
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