Abstract:Two cyclen-based multidentate N,O ligands, 1,4,7,10-tetrazazcyclododecane-N, N 0 ,N 00 ,N 000 -tetra-p-methylbenzoic acid (H 4 L 1 ) and 1,4,7,10-tetrazazcyclododecane-N,N 0 ,N 00 ,N 000 -tetra-p-cinnamic acid (H 4 L 2 ), were reacted with Zn (II) salts leading to a four-fold interpenetrated 3D binodal PtS-type network {[Zn 2 (HL 1 ) Cl]Á5H 2 O} n (Zn-1) along with a 1D ribbon-like polymeric chain {[Zn 3 (HL 2 ) Cl 3 (H 2 O) 2 ]Á2CH 3 COCH 3 Á3H 2 O} n (Zn-2). Both two compounds exhibited excellent water stabi… Show more
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