2021
DOI: 10.1016/j.snb.2021.130074
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Fluorescent nitrogen-doped Ti3C2 MXene quantum dots as a unique “on-off-on” nanoprobe for chrominum (VI) and ascorbic acid based on inner filter effect

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Cited by 56 publications
(32 citation statements)
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“…Moreover, at higher quencher concentrations (> 10 µM concentration), the uorophores are surrounded by the quencher ions, which blocks the radiative path of the uorophores causing rapid uorometric quenching. Such phenomenon is known as inner lter effect [41][42][43]. Herein, simultaneous occurrence of the photoinduced electron transfer and inner lter effect is obtained at higher Cr (VI) concentrations, which justi es the exponential S-V plot.…”
Section: Detection Mechanism Of the Sensing Probementioning
confidence: 81%
“…Moreover, at higher quencher concentrations (> 10 µM concentration), the uorophores are surrounded by the quencher ions, which blocks the radiative path of the uorophores causing rapid uorometric quenching. Such phenomenon is known as inner lter effect [41][42][43]. Herein, simultaneous occurrence of the photoinduced electron transfer and inner lter effect is obtained at higher Cr (VI) concentrations, which justi es the exponential S-V plot.…”
Section: Detection Mechanism Of the Sensing Probementioning
confidence: 81%
“…In previous reports, the inner filter effect (IFE) and FRET are considered as two major mechanisms in the luminescence quenching. [52][53][54] In order to discriminate between the two mechanisms, luminescence decays were subsequently measured. As seen from Fig.…”
Section: Resultsmentioning
confidence: 99%
“…The bands at 951, 1037, 1083, 1631 and 3014 cm −1 are attributed to the stretching vibrations of C-C, C-F, C-N, CvO and C-H, respectively. 17,23,34 Other strong bands in the regions around 1486 and 3425 cm −1 are assigned to the -OH bending and stretching vibrations, respectively. 35 In particular, compared with the MQDs, the significantly stronger bands at 1378, 1531 and 3120 cm −1 for the N-MQDs are associated with the C-N stretching vibration, N-H bending vibration and N-H stretching vibration, demonstrating the increased amount of amino groups on the N-MQDs.…”
Section: Characterization Of Qdsmentioning
confidence: 99%