Fluorescence spectroscopy for wastewater monitoring: A review

Cârstea, Elfrida M.; Bridgeman, John; Baker, Andy; Reynolds, Darren M.

doi:10.1016/j.watres.2016.03.021

Cited by 505 publications

(241 citation statements)

References 133 publications

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“…Water 2017, 9, 409 8 of 11 [11]. Overall, the JS wastewater contained a large amount of biodegradable components (i.e., the tryptophan-like C2 component) and exhibited an apparent compositional change of wastewater organic matter during the biodegradation process, whereas the DS and HP wastewaters contained mostly nonbiodegradable components.…”

Section: Feem-parafacmentioning

confidence: 99%

“…It could be removed by physico-chemical treatments, such as coagulation, but not entirely with a biological treatment system. The fulvic-like C4 component was reported to be recalcitrant in a conventional activated sludge system, because it is considered non-biodegradable [11,29,30]. …”

Section: Feem-parafacmentioning

confidence: 99%

“…Because many chemical dyes are based on aromatic or heterocyclic ring structures, which are considered non-biodegradable, industrial discharge from dyeing factories likely contains substantial amounts of NBDSCOD. In addition, industrial discharge from paper mill factories was reported to contain a large amount of lignin and lignin derivatives, which are also known to be non-biodegradable, and hence, increase the amount of NBDSCOD [10,11]. An advanced oxidation process might be required to degrade NBDSCOD containing aromatic compounds from dyeing and paper mill factories [9,12].…”

Section: Introductionmentioning

confidence: 99%

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Characteristics and Biodegradability of Wastewater Organic Matter in Municipal Wastewater Treatment Plants Collecting Domestic Wastewater and Industrial Discharge

Choi

Baek

Kim

et al. 2017

Water

108

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Municipal wastewater treatment plants (WWTPs) in Korea collect and treat not only domestic wastewater, but also discharge from industrial complexes. However, some industrial discharges contain a large amount of non-biodegradable organic matter, which cannot be treated properly in a conventional biological WWTP. This study aimed to investigate the characteristics and biodegradability of the wastewater organic matter contained in the industrial discharges and to examine the fate of the industrial discharges in a biological WWTP. In contrast to most previous studies targeting a specific group of organic compounds or traditional water quality indices, such as biological oxygen demand (BOD) and chemical oxygen demand (COD), this study was purposed to quantify and characterize the biodegradable and nonbiodegradable fractions of the wastewater organic matter. Chemical oxygen demand (COD) fractionation tests and fluorescence spectroscopy revealed that the industrial discharge from dyeing or pulp mill factories contained more non-biodegradable soluble organic matter than did the domestic wastewater. Statistical analysis on the WWTPs' monitoring data indicated that the industrial discharge containing non-biodegradable soluble organic matter was not treated effectively in a biological WWTP, but was escaping from the system. Thus, industrial discharge that contained non-biodegradable soluble organic matter was a major factor in the decrease in biodegradability of the discharge, affecting the ultimate fate of wastewater organic matter in a biological WWTP. Further application of COD fractionation and fluorescence spectroscopy to wastewaters, with various industrial discharges, will help scientists and engineers to better design and operate a biological WWTP, by understanding the fate of wastewater organic matter.

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Section: Feem-parafacmentioning

confidence: 99%

Section: Feem-parafacmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

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Characteristics and Biodegradability of Wastewater Organic Matter in Municipal Wastewater Treatment Plants Collecting Domestic Wastewater and Industrial Discharge

Choi

Baek

Kim

et al. 2017

Water

108

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“…First, while HPLC analyses allow the determination of dissolved Trp concentrations only, the MiniFluo also record fluorescence due to Trp bounded to particulate matter that may lead to an increase in the total Trplike fluorescence signal in seawater. Second, as highlighted by Carstea et al (2016), other organic compounds, such as lignins, may also fluoresce in the Trp spectral domain. Discrete molecular analyses of dissolved tryptophan combined with MiniFluo measurements would help understanding the real contribution of dissolved tryptophan compound in the MiniFluo-derived Trplike fluorescence.…”

Section: Confidence In Minifluo Measurementsmentioning

confidence: 99%

“…In these environments, Trp-like fluorophore, which is usually well correlated to biological oxygen demand, would originate from bacterial activities. Hence, it has been used as a tracer of sewage contamination and for online monitoring in wastewater treatment works (Petrenko et al, 1997;Baker et al, 2004;Hudson et al, 2008;Carstea et al, 2016). However, Trp is not only associated with wastewater bacterial activities, and is now becoming recognized as a by-product of marine primary production.…”

Section: Introductionmentioning

confidence: 99%

A New Glider-Compatible Optical Sensor for Dissolved Organic Matter Measurements: Test Case from the NW Mediterranean Sea

Cyr

Tedetti

Besson³

et al. 2017

Front. Mar. Sci.

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The MiniFluo-UV is a new glider-compatible optical sensor for measurements of dissolved organic matter (DOM) in natural waters. The working principle, sensor design and challenges faced during the validation phase are reported. The first in situ application of the sensor during three glider deployments in the NW Mediterranean sea (spring, summer, and fall) are also presented. For these campaigns, the two channels of the sensor were adjusted to target Tryptophan-like (excitation/emission wavelengths λ Ex /λ Em : 275/340 nm) and Phenanthrene-like (λ Ex /λ Em : 255/360 nm) fluorescence. These were chosen because they represent fluorophores of interest commonly found in seawater. While Tryptophan (an amino-acid believed to be a by-product of biological activity) is naturally found in the ocean, Phenanthrene (a polycyclic aromatic hydrocarbon) is mainly introduced in the environment by human activities. The addition of these variables to more common physical and biogeochemical glider measurements reveals new features of DOM dynamics in the Mediterranean Sea. For example, the temporal and spatial decoupling between Tryptophan-like and Chl-a fluorescence suggests that the former is not only a marker of phytoplankton activity, but could also give more subtle information on the microbial processes occurring. The identification of a Phenanthrene-like layer just below the pycnocline at all seasons also raises questions on the mechanisms driving its presence in the Mediterranean. Knowing that the role of ocean DOM on atmospheric carbon sequestration is becoming clearer, the high spatiotemporal resolution possible with this new sampling strategy may represents a key step toward our deep understanding of DOM dynamics and its role on the biological pump.

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