Fluid-induced plastic deformation in the crustal Austroalpine system (Western Italian Alps): a petrologic and fluid inclusion analysis di Nadia MALASPINA, Marco SCAMBELLURI, Giorgio PENNACCHIONI &amp; Chiara. SPAGNOLO

Malaspina, Nadia; Scambelluri, Marco; Pennacchioni, Giorgio; Spagnolo, Chiara

doi:10.3301/ijg.2010.24

Cited by 3 publications

References 31 publications

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Tectono-metamorphic map of the Mont Morion Permian metaintrusives (Mont Morion—Mont Collon—Matterhorn Complex, Dent Blanche Unit), Valpelline—Western Italian Alps

Roda

Zucali

2011

Journal of Maps

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The presented map displays the structural and metamorphic evolution of lithotypes from pre-Permian to present. We distinguish pre-Permian rocks (e.g., amphibolite, biotite-bearing gneiss and acid granulite) preserved as roof pendants (i.e., xenoliths) within Permian intrusives. Permian intrusives and hosted xenoliths are then re-equilibrated during Alpine evolution, producing coronitic to mylonitic metaintrusives, due to meter to kilometer-scale fabric gradients, and associated white mica-, glaucophane-bearing gneiss. The map also shows the traces of the superimposed foliations and the fold axial planes. The traces are distinguished on the basis of their relative chronology and mineralogical support. This information, reported on a single map, allows us to reconstruct the successive stages of this fragment belonging to the African plate continental crust, from the pre-Alpine extension, recorded by granulite-to amphibolite-facies xenolits, to the Permian intrusive phase (e.g., Mont Morion, Mont Collon and Matterhorn intrusives) lasting with the Alpine subduction-collision related evolution. The Mont Morion, part of the Mont Morion-Mont Collon-Matterhorn Complex of the Dent Blanche unit, may be interpreted as a multi-stadial Alpine km-scale shear zone, where Permian intrusive rocks are transformed into white mica chlorite-bearing or glaucophane-bearing gneisses along high-strain horizons (100 m-thick), while within low-strain cores (100-to 1000 m-thick), meta-intrusives preserve igneous features and xenoliths of amphibolites, acid granulites and biotite-bearing gneisses. In this paper, an outcrop tectono-metamorphic map (1:10,000 scale) is presented, based upon fieldwork at 1:5,000 together with an interpretative map (1:15,000 scale), in which three dimensional relationships are described, and micro-to mesoscopic fabric types are shown, corresponding to finite strain states recorded by rocks.

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Tectono-metamorphic map of the Mont Morion Permian metaintrusives (Mont Morion—Mont Collon—Matterhorn Complex, Dent Blanche Unit), Valpelline—Western Italian Alps

Roda

Zucali

2011

Journal of Maps

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U–Pb geochronology of epidote by LA–ICP–MS as a tool for dating hydrothermal-vein formation

Peverelli

Ewing

Rubatto

et al. 2020

Preprint

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Abstract. Monoclinic epidote is a low-µ (µ = 283U / 204Pb) mineral occurring in a variety of geological environments, participating in many metamorphic reactions and stable throughout a wide range of pressure–temperature conditions. Despite containing fair amounts of U, its use as a U–Pb geochronometer has been hindered by the commonly high contents of initial Pb with isotopic compositions that cannot be assumed a priori. We present U–Pb geochronology of hydrothermal-vein epidote spanning a wide range of Pb (3.9–190 µg g−1), Th (0.009–38 µg g−1) and U (2.6–530 µg g−1) contents and with µ values between 7–510 from the Albula area (eastern Swiss Alps), from the Grimsel area (central Swiss Alps) and from the Heyuan fault (Guangdong province, China). The investigated epidote samples show appreciable fractions of initial Pb that vary to different extents. A protocol has been developed for in situ U–Pb dating of epidote by spot-analysis laser ablation inductively coupled plasma mass spectrometry (LA–ICP–MS) with a magmatic allanite as primary reference material. The suitability of the protocol and the reliability of the measured isotopic ratios have been ascertained by independent measurements of 238U / 206Pb and 207Pb / 206Pb ratios respectively by quadrupole and multicollector ICP–MS applied to epidote micro-separates digested and diluted in acids. For age calculation, we used the Tera–Wasserburg (207Pb / 206Pb–238U / 206Pb) diagram, which does not require corrections for initial Pb and provides the initial 207Pb / 206Pb ratio if all intra-sample analyses are co-genetic. Petrographic and microstructural data indicate that the calculated ages date the crystallization of vein epidote from a hydrothermal fluid and that the U–Pb system was not reset to younger ages by later events. Vein epidote from the Albula area formed in the Paleocene (62.7 ± 3.0 Ma) and is related to Alpine greenschist-facies metamorphism. The Miocene (19.1 ± 4.0 Ma and 16.9 ± 3.7 Ma) epidote veins from the Grimsel area formed during the Handegg phase (22–17 Ma) of the Alpine evolution of the Aar Massif. Identical initial 207Pb / 206Pb ratios reveal homogeneity in Pb isotopic compositions of the fluid across ca. 200 m. Vein epidote from the Heyuan fault is Cretaceous in age (108.1 ± 8.4 Ma) and formed during the early movements of the fault. In situ U–Pb analyses of epidote returned reliable ages of otherwise undatable epidote-quartz veins. The Tera–Wasserburg approach has proven pivotal for in situ U–Pb dating of epidote and the decisive aspect for low age uncertainties is the variability in intra-sample initial Pb fractions.

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U − Pb geochronology of epidote by laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) as a tool for dating hydrothermal-vein formation

et al. 2021

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Abstract. Epidote – here defined as minerals belonging to the epidote–clinozoisite solid solution – is a low-μ (μ=238U/204Pb) mineral occurring in a variety of geological environments and participating in many metamorphic reactions that is stable throughout a wide range of pressure–temperature conditions. Despite containing fair amounts of U, its use as a U−Pb geochronometer has been hindered by the commonly high contents of initial Pb, with isotopic compositions that cannot be assumed a priori. We present a U−Pb geochronology of hydrothermal-vein epidote spanning a wide range of Pb (3.9–190 µg g−1), Th (0.01–38 µg g−1), and U (2.6–530 µg g−1) contents and with μ values between 7 and 510 from the Albula area (eastern Swiss Alps), from the Grimsel area (central Swiss Alps), and from the Heyuan fault (Guangdong Province, China). The investigated epidote samples show appreciable fractions of initial Pb contents (f206=0.7–1.0) – i.e., relative to radiogenic Pb – that vary to different extents. A protocol has been developed for in situ U−Pb dating of epidote by spot-analysis laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) with a magmatic allanite as the primary reference material. The suitability of the protocol and the reliability of the measured isotopic ratios have been ascertained by independent measurements of 238U/206Pb and 207Pb/206Pb ratios, respectively, with quadrupole and multicollector ICP-MS applied to epidote micro-separates digested and diluted in acids. For age calculation, we used the Tera–Wasserburg (207Pb/206Pb versus 238U/206Pb) diagram, which does not require corrections for initial Pb and provides the initial 207Pb/206Pb ratio. Petrographic and microstructural data indicate that the calculated ages date the crystallization of vein epidote from a hydrothermal fluid and that the U−Pb system was not reset to younger ages by later events. Vein epidote from the Albula area formed in the Paleocene (62.7±3.0 Ma) and is related to Alpine greenschist-facies metamorphism. The Miocene (19.2±4.3 and 16.9±3.7 Ma) epidote veins from the Grimsel area formed during the Handegg deformation phase (22–17 Ma) of the Alpine evolution of the Aar Massif. Identical initial 207Pb/206Pb ratios reveal homogeneity in Pb isotopic compositions of the fluid across ca. 100 m. Vein epidote from the Heyuan fault is Cretaceous in age ( 107.2±8.9 Ma) and formed during the early movements of the fault. In situ U−Pb analyses of epidote returned reliable ages of otherwise undatable epidote–quartz veins. The Tera–Wasserburg approach has proven pivotal for in situ U−Pb dating of epidote, and the decisive aspect for low age uncertainties is the variability in intra-sample initial Pb fractions.

show abstract

Fluid-induced plastic deformation in the crustal Austroalpine system (Western Italian Alps): a petrologic and fluid inclusion analysis di Nadia MALASPINA, Marco SCAMBELLURI, Giorgio PENNACCHIONI & Chiara. SPAGNOLO

Cited by 3 publications

References 31 publications

Tectono-metamorphic map of the Mont Morion Permian metaintrusives (Mont Morion—Mont Collon—Matterhorn Complex, Dent Blanche Unit), Valpelline—Western Italian Alps

Tectono-metamorphic map of the Mont Morion Permian metaintrusives (Mont Morion—Mont Collon—Matterhorn Complex, Dent Blanche Unit), Valpelline—Western Italian Alps

U–Pb geochronology of epidote by LA–ICP–MS as a tool for dating hydrothermal-vein formation

U − Pb geochronology of epidote by laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) as a tool for dating hydrothermal-vein formation

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