The potential of using granite dust as reinforcement into polybenzoxazine matrix was investigated. In this article, novel granite powder waste-reinforced bisphenol-A aniline-based benzoxazine composites were prepared using solution blending technique by varying the content of granite powder from 10 to 40 wt%. The effect of the granite powder content on the thermal, structural, dimensional, and morphological properties of granite powder/polybenzoxazine composites have been investigated. Thermogravimetric analysis (TGA) was performed on the composite samples. Char yield of the composites increased from 44.55 to 67.70% for increasing filler content from 10 to 40wt%, whereas 22% for pure polybenzoxazine. The maximum weight loss temperatures of the composites were analyzed from derivative of thermogravimetric analysis (DTG). Limiting oxygen index (LOI) values also increased as granite powder content increased. Structural properties of benzoxazine, polybenzoxazine, and composites were observed with Fourier-transform infrared spectroscopy (FTIR). Dimensional stability of the composites was investigated through the water absorption test up to 30 days. The composites exhibited zero percent water absorption. Micro-hardness of the composites increased from 17.45 to 78.66% for increasing filler content from 10-40 wt% when compared with pristine polybenzoxazine. The morphological analysis using scanning electron microscopy (SEM) showed the distribution of filler, aggregate formation, compatibility between polybenzoxazine and granite powder. Overall, the importance of using granite powder waste as reinforcement in polybenzoxazine composites revealed from results of the structural, dimensional, and morphological analysis along with the improvement in thermal properties and micro-hardness.