2017
DOI: 10.1021/acsami.7b03929
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Flexible Semitransparent Energy Harvester with High Pressure Sensitivity and Power Density Based on Laterally Aligned PZT Single-Crystal Nanowires

Abstract: A flexible semitransparent energy harvester is assembled based on laterally aligned Pb(ZrTi)O (PZT) single-crystal nanowires (NWs). Such a harvester presents the highest open-circuit voltage and a stable area power density of up to 10 V and 0.27 μW/cm, respectively. A high pressure sensitivity of 0.14 V/kPa is obtained in the dynamic pressure sensing, much larger than the values reported in other energy harvesters based on piezoelectric single-crystal NWs. Furthermore, theoretical and finite element analyses a… Show more

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Cited by 49 publications
(22 citation statements)
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References 46 publications
(78 reference statements)
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“…The most popular piezoelectric materials used in e-skin sensors, energy harvesters, and other types of sensors are lead zirconate titanate (PZT) [ 89 , 90 , 91 ], zinc oxide (ZnO) [ 68 , 87 , 92 , 93 , 94 , 95 , 96 , 97 , 98 , 99 , 100 , 101 ], barium titanate (BaTiO 3 ) [ 102 , 103 ], poly(vinylidene difluoride) (PVDF) and its co-polymers like poly[(vinylidenefluoride-co-trifluoroethylene] [P(VDF-TrFE)] and poly(vinylidene fluoride-co-hexafluoropropene) [P(VDF-HFP)] [ 88 , 99 , 102 , 103 , 104 , 105 , 106 , 107 , 108 ], and their piezoelectric coefficient, d 33 , can be found in Table 1 . The relation between the d 33 and the output of a piezoelectric sensor can be established by Equation (2): where V is the voltage produced by the sensor, C is the capacitance, and F is the force applied to the sensor [ 109 ].…”
Section: Pressure Sensorsmentioning
confidence: 99%
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“…The most popular piezoelectric materials used in e-skin sensors, energy harvesters, and other types of sensors are lead zirconate titanate (PZT) [ 89 , 90 , 91 ], zinc oxide (ZnO) [ 68 , 87 , 92 , 93 , 94 , 95 , 96 , 97 , 98 , 99 , 100 , 101 ], barium titanate (BaTiO 3 ) [ 102 , 103 ], poly(vinylidene difluoride) (PVDF) and its co-polymers like poly[(vinylidenefluoride-co-trifluoroethylene] [P(VDF-TrFE)] and poly(vinylidene fluoride-co-hexafluoropropene) [P(VDF-HFP)] [ 88 , 99 , 102 , 103 , 104 , 105 , 106 , 107 , 108 ], and their piezoelectric coefficient, d 33 , can be found in Table 1 . The relation between the d 33 and the output of a piezoelectric sensor can be established by Equation (2): where V is the voltage produced by the sensor, C is the capacitance, and F is the force applied to the sensor [ 109 ].…”
Section: Pressure Sensorsmentioning
confidence: 99%
“…PZT and ZnO are commonly integrated into sensors in the form of thin films or nano/micro-structures to minimize their brittle nature [ 54 , 87 , 89 , 91 , 97 , 100 ]. PVDF polymers are highly flexible, yet require a poling process to maximize their typically low d 33 constant [ 54 , 99 , 102 , 103 , 105 , 106 , 107 , 108 ].…”
Section: Pressure Sensorsmentioning
confidence: 99%
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“…Achieving efficient conversion of mechanical energy into electricity is, as always, the endless impetus in searching or designing applicable structural materials toward NG. Up to now, kinds of materials are developed to satisfy the construction of high‐performance NGs, including ZnO nanowire arrays, lead zirconate titanate (PZT) nanofibers, BaTiO 3 nanomaterials, and piezoelectric PVDF nanofibers, etc.…”
Section: Applications Via Ehd Direct‐writingmentioning
confidence: 99%
“…The advantage for PZT nanowire single crystal is possibly transferred onto flexible substrates, highly elastic and resistant to fatigue, and largely enhanced energy conversion efficiencies and piezoelectric constants because of the absence of domain boundaries which can pin up the dipole moments [112][113][114]. A flexible semitransparent energy harvesting with highly open voltage and stable power density of 10 V and 0.27 μW/cm 2 was fabricated in visible and near-infrared light regions, composed with laterally aligned Pb(Zr 0.52 Ti 0.48 )O 3 single nanowires and planar interdigitated Pt/Ti electrodes to avoid the decrease of dielectric constant from conventional sandwich configuration [115].…”
Section: Ferroelectric Materialsmentioning
confidence: 99%