Ice accumulation on insulators of overhead transmission lines and substations has been recognized as a major problem which may cause insulator flashover and power outages. This phenomenon starts with corona discharge activity and continues with the formation of partial arcs which may result in flashover. Due to the complexity of the process, resulting from surface interaction of discharge with the water film on the ice surface, is not yet fully understood. As for any other type of discharge, the knowledge of some parameters such as temperature and concentration of different species is necessary in order to describe the mechanisms involved. Moreover, to develop mathematical models for discharge propagation, an estimation of discharge channel conductivity is necessary. The current flows through this conductive channel and supplies the energy needed to sustain the ionization activity inside the channel. The conductivity of discharge channel is directly related to its temperature, which illustrates the need for discharge temperature measurements. Up to now, for an arc over an ice surface the temperature has been assumed to have a constant value of 5,000 K, but without any experimental support.The existence of Local Thermodynamic Equilibrium (LTE) is another important aspect for proposing theories and models, but this has not yet been verified for flashover on icecovered insulators. The verification of LTE condition requires information about temperature and concentration of different species, electron density and ionization level.The objective of this research is to augment our knowledge of flashover on icecovered insulators by measuring and calculating several important discharge column parameters. Measurement of rotational and excitation temperatures, and electron density during arc propagation are the first steps. The effect of discharge current, voltage type and polarity on the variation of the mentioned arc parameters should be also studied.Based on these data, the LTE condition could be examined.Spectroscopic plasma diagnostic is a non-destructive test method used to achieve the stated objectives. The emitted light from an arc over an ice surface was transmitted to a spectrometer. The time-resolved recorded spectra of arc were used to study the nature and concentration of ionized species. The gas and electron temperatures and electron densities were also measured using Boltzmann and Stark broadening methods.Measured rotational temperatures were found to vary from 4,000 K to 6,500 K, while the current increased from 200 mA to 700 mA during the discharge propagation. It was observed that under similar experimental conditions, the arc current intensity of DC+ arcs were hotter than that of DC-. Moreover, arc temperatures under AC voltage were lower than those of DC+, and close to that of DC-. The excitation temperature was measured at about 9,000 K and does not vary significantly with discharge current. As current increases, electron densities increased as well. For currents ranging from 200 mA to 700 mA, ...