Phosphorus flame retardants are a broad and expanding class of additive or reactive organic or inorganic compounds used to improve the fire safety of flammable materials such as plastics, textiles, wood, paper, and other flammable materials.
In this article, their modes of action (vapor phase, condensed phase) and interactions are described, then specific classes of phosphorus flame retardants and significant compounds in each class are discussed. Attention is given to the chemistry and mode of use in commercial practice. Polymers with built‐in phosphorus structures such as epoxy resins and polyesters are given attention.
Health, safety, and environmental aspects are discussed as are commercial trends.