Flame-retardant finishing of cotton fabric by surface-initiated photochemically induced atom transfer radical polymerization

Zain, Gamal; Jordanov, Igor; Bischof, Sandra; Magovac, Eva; Šišková, Alena Opálková; Vykydalová, Anna; Kleinová, Angela; Mičušík, Matej; Mosnáčková, Katarína; Nováčiková, Jana; Mosnáček, Jaroslav

doi:10.1007/s10570-022-04982-z

Cellulose

2022

DOI: 10.1007/s10570-022-04982-z

|View full text |Cite

Flame-retardant finishing of cotton fabric by surface-initiated photochemically induced atom transfer radical polymerization

Gamal Zain

Igor Jordanov

Sandra Bischof

et al.

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2023

2024

Publication Types

Select...

Article6

Relationship

Self Cite0

Independent6

Authors

Journals

Cited by 10 publications

(1 citation statement)

References 44 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Three characteristic peaks at 3410, 2897 and 1116 cm −1 were observed in the control cotton, corresponding to O-H, C-H and C-O-C stretching vibrations, respectively[25]. The five peaks at 3182, 2393, 1282, 1054 and 777 cm −1 corresponding to N-H, P-OH, P=O, P-O-C and P-N, respectively, were observed in the ATPEPDPA curve, which is consistent with the ATPEPDPA structure[26][27][28]. In the ATPEPDPA-treated cotton (FRC-20) curve, except for characteristic peaks of cotton fibers, three characteristic peaks appeared at 1241, 1058 and 771 cm −1 , representing P=O, P-O-C and P-N, respectively.…”

supporting

confidence: 78%

Phosphamide-Based Washing-Durable Flame Retardant for Cotton Fabrics

Li,

Zhang,

Zhang

2024

Materials

View full text Add to dashboard Cite

A formaldehyde-free reactive flame retardant, an ammonium salt of triethylenetetramine phosphoryl dimethyl ester phosphamide phosphoric acid (ATPEPDPA), was synthesized and characterized using nuclear magnetic resonance (NMR). Fourier transform infrared spectroscopy test (FT-IR), durability test and scanning electron microscopy (SEM) results suggested that ATPEPDPA was successfully grafted on cotton fabrics through a -N-P(=O)-O-C covalent bond. Moreover, the limiting oxygen index (LOI) value of 20 wt% ATPEPDPA-treated cotton was 44.6%, which met stringent washing standard after 50 laundering cycles (LCs). The high washing resistance of the ATPEPDPA-treated cotton was due to the p-π conjugation between the N atom and the P(=O) group in the flame-retardant molecule, which strengthened the stability of the -N-P(=O)-O-C bonds between ATPEPDPA and cellulose, and the -N-P(=O)-(O-CH3)2 groups in the ATPEPDPA. The cone calorimetric test showed that the treated cotton had excellent flame retardance. In addition, the TG and TG-IR tests suggested that ATPEPDPA performed a condensed flame retardance mechanism. Furthermore, the physical properties and hand feel of the treated cotton were well maintained. These results suggested that introducing -N-P(=O)-(O-CH3)2 and -N-P(=O)-(ONH4)2 groups into ATPEPDPA could significantly increase the fire resistance and durability of cotton fabrics.

show abstract

supporting

confidence: 78%

Phosphamide-Based Washing-Durable Flame Retardant for Cotton Fabrics

Li,

Zhang,

Zhang

2024

Materials

View full text Add to dashboard Cite

show abstract

A durable formaldehyde-free flame retardant containing phosphamide and ammonium phosphate for cotton fabrics

Ding,

Liu,

Liu

et al. 2023

Cellulose

View full text Add to dashboard Cite

DNA used as a “double helix” template for synthesis of flexible silver strings for conductive and electromagnetic shielding of cotton fabrics

Wang,

Xu,

Zhang

et al. 2024

Cellulose

View full text Add to dashboard Cite

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

hi@scite.ai

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Flame-retardant finishing of cotton fabric by surface-initiated photochemically induced atom transfer radical polymerization

Cited by 10 publications

References 44 publications

Phosphamide-Based Washing-Durable Flame Retardant for Cotton Fabrics

Phosphamide-Based Washing-Durable Flame Retardant for Cotton Fabrics

A durable formaldehyde-free flame retardant containing phosphamide and ammonium phosphate for cotton fabrics

DNA used as a “double helix” template for synthesis of flexible silver strings for conductive and electromagnetic shielding of cotton fabrics

Contact Info

Product

Resources

About